Synthesis of NOBIN derivatives for asymmetric catalysis

被引:77
作者
Ding, KL [1 ]
Guo, HC [1 ]
Li, X [1 ]
Yuan, Y [1 ]
Wang, Y [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
基金
中国国家自然科学基金;
关键词
NOBIN; asymmetric catalysis; optical resolution; diethyl zinc addition; allylic addition; allylic substitution; hetero-Diels-Alder reaction;
D O I
10.1007/s11244-005-3816-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This account highlighted the recent advances of our research on the synthesis of enantiopure 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN) and its derivatives as well as their applications in asymmetric catalysis, including diethyl zinc addition to aldehydes, allylic addition to aldehydes, allylic substitutions, and hetero-Diels-Alder reactions.
引用
收藏
页码:105 / 116
页数:12
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