Enhancement of β-crystalline phase of poly(vinylidene fluoride) in the presence of hyperbranched copolymer wrapped multiwalled carbon nanotubes

被引：38

作者：

He, Linghao ^{[2
]}

Sun, Jing ^{[2
]}

Wang, Xiuxin ^{[1
]}

Yao, Lu ^{[2
]}

Li, Jialong ^{[2
]}

Song, Rui ^{[1
,2
]}

Hao, Yongmei ^{[1
]}

He, Yujian ^{[1
]}

Huang, Wei ^{[3
]}

机构：

[1] Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China

[2] Zhengzhou Univ Light Ind, State Key Lab Surface & Interface Sci, Zhengzhou 450005, Peoples R China

[3] Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100080, Peoples R China

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2011年 / 363卷 / 01期

关键词：

Poly(vinylidene fluoride); Multiwalled carbon nanotubes; Crystallization; Hyperbranched copolymer; POLYVINYLIDENE DIFLUORIDE FIBERS; THIN-FILMS; MECHANICAL-PROPERTIES; MODIFIED SILICATE; NANOCOMPOSITES; MORPHOLOGY; TRANSFORMATION; NANOCLAY; NANOFIBERS; DEPOSITION;

D O I：

10.1016/j.jcis.2011.07.042

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Many efforts have been performed on the poly(vinylidene fluoride), PVDF, due to its piezoelectric, pyroelectric and ferroelectric potentials. In this regard, how to fabricate the PVDF with high content of beta-phase, which is also the direct contribution to PVDFs prominent property, becomes a critical issue. In this study, starting with the alpha-phase dominated sample, the PVDF with extremely high content of beta-crystalline phase was obtained by the incorporation of multiwalled carbon nanotubes (MWCNTs) modified by hyperbranched copolymers (HBCs). We proved that, via XRD. DSC as well as the structural characterizations from the polarized optical microscopy and transmission electron microscopy (TEM), the success of this strategy was ascribed to the enhanced dispersibility and stability of MWCNTs endowed by the HBCs, which significantly favors the formation of the beta-crystalline phase of PVDF. (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：122 / 128

页数：7

共 45 条

[1] Enhanced ferroelectric phase content of polyvinylidene difluoride fibers with the addition of magnetic nanoparticles [J].

Andrew, J. S. ;

Clarke, D. R. .

LANGMUIR, 2008, 24 (16) :8435-8438

[2] Effect of electrospinning on the ferroelectric phase content of polyvinylidene difluoride fibers [J].

Andrew, J. S. ;

Clarke, D. R. .

LANGMUIR, 2008, 24 (03) :670-672

[3] Electrospinning of polyvinylidene difluoride-based nanocomposite fibers [J].

Andrew, J. S. ;

Mack, J. J. ;

Clarke, D. R. .

JOURNAL OF MATERIALS RESEARCH, 2008, 23 (01) :105-114

[4] Noncovalent and nonspecific molecular interactions of polymers with multiwalled carbon nanotubes [J].

Baskaran, D ;

Mays, JW ;

Bratcher, MS .

CHEMISTRY OF MATERIALS, 2005, 17 (13) :3389-3397

[5] Nanocomposites of poly(vinylidene fluoride) with organically modified silicate [J].

Buckley, J ;

Cebe, P ;

Cherdack, D ;

Crawford, J ;

Ince, BS ;

Jenkins, M ;

Pan, JJ ;

Reveley, M ;

Washington, N ;

Wolchover, N .

POLYMER, 2006, 47 (07) :2411-2422

[6] On the structure and morphology of polyvinylidene fluoride-nanoclay nanocomposites [J].

Dillon, DR ;

Tenneti, KK ;

Li, CY ;

Ko, FK ;

Sics, I ;

Hsiao, BS .

POLYMER, 2006, 47 (05) :1678-1688

[7] Influence of the β-phase content and degree of crystallinity on the piezo- and ferroelectric properties of poly(vinylidene fluoride) [J].

Gomes, J. ;

Nunes, J. Serrado ;

Sencadas, V. ;

Lanceros-Mendez, S. .

SMART MATERIALS AND STRUCTURES, 2010, 19 (06)

[8] Determination of the α, β, and γ crystalline phases of poly(vinylidene fluoride) films prepared at different conditions [J].

Gregorio, R .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 100 (04) :3272-3279

[9] Effect of Multi-Walled Carbon Nanotubes on Crystallization, Thermal, and Mechanical Properties of Poly(vinylidene fluoride) [J].

He, Linghao ;

Xu, Qun ;

Hue, Chengwu ;

Song, Rui .

POLYMER COMPOSITES, 2010, 31 (05) :921-927

[10] Modification of Carbon Nanotubes Using Poly(vinylidene fluoride) with Assistance of Supercritical Carbon Dioxide: The Impact of Solvent [J].

He, Linghao ;

Zheng, Xiaoli ;

Xu, Qun .

JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (16) :5257-5262

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