Hard Carbon Fibers Pyrolyzed from Wool as High-Performance Anode for Sodium-Ion Batteries

被引:39
作者
Zhu, Xiaoming [1 ]
Li, Qian [2 ]
Qiu, Shen [3 ]
Liu, Xiaoling [1 ]
Xiao, Lifen [4 ]
Ai, Xinping [3 ]
Yang, Hanxi [3 ]
Cao, Yuliang [3 ]
机构
[1] Hubei Univ Sci & Technol, Sch Nucl Technol Chem & Biol, Hubei Collaborat Innovat Ctr Nonpower Nucl Techno, Xianning 437100, Peoples R China
[2] Wuhan Text Univ, Coll Chem & Chem Engn, Wuhan 430073, Peoples R China
[3] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Peoples R China
[4] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China
关键词
HIGH-CAPACITY; LOW-COST; LITHIUM; NANOFIBERS; MICROSPHERES; ELECTRODES; NANOPARTICLES; GRAPHITE; LIFE;
D O I
10.1007/s11837-016-2064-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, we first demonstrate that the wool from worn-out clothes can serve as a low-cost and easy-to-collect precursor to preparing high-performance hard carbons for Na-ion batteries. Morphological characterizations demonstrate that this wool-derived hard carbon presents well-defined and homogeneously dispersed fiber networks. X-ray diffraction results combined with high-resolution transmission electron microscopy analysis reveal that the interlayer space (d(002)) of the graphitic layers is 0.376 nm, sufficient for Na insertion into the stacked graphene layers. Electrochemical results show that the wool-derived hard carbon can deliver a high capacity of 303 mAh g(-1) and excellent cycle stability over 80 cycles. This satisfactory electrochemical performance and easy synthetic procedure make it a promising anode material for practical SIBs.
引用
收藏
页码:2579 / 2584
页数:6
相关论文
共 42 条
[1]   Carbon microspheres obtained from resorcinol-formaldehyde as high-capacity electrodes for sodium-ion batteries [J].
Alcántara, R ;
Lavela, P ;
Ortiz, GF ;
Tirado, JL .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (04) :A222-A225
[2]   Low-Cost, Dendrite-Blocking Polymer-Sb2O3 Separators for Lithium and Sodium Batteries [J].
Ansari, Younes ;
Guo, Bingkun ;
Cho, Joon Hee ;
Park, Kyusung ;
Song, Jie ;
Ellison, Christopher J. ;
Goodenough, John B. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (10) :A1655-A1661
[3]   Self-organized amorphous TiO2 nanotube arrays on porous Ti foam for rechargeable lithium and sodium ion batteries [J].
Bi, Zhonghe ;
Paranthaman, M. Parans ;
Menchhofer, Paul A. ;
Dehoff, Ryan R. ;
Bridges, Craig A. ;
Chi, Miaofang ;
Guo, Bingkun ;
Sun, Xiao-Guang ;
Dai, Sheng .
JOURNAL OF POWER SOURCES, 2013, 222 :461-466
[4]   Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements [J].
Bommier, Clement ;
Luo, Wei ;
Gao, Wen-Yang ;
Greaney, Alex ;
Ma, Shengqian ;
Ji, Xiulei .
CARBON, 2014, 76 :165-174
[5]   Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].
Cao, Yuliang ;
Xiao, Lifen ;
Sushko, Maria L. ;
Wang, Wei ;
Schwenzer, Birgit ;
Xiao, Jie ;
Nie, Zimin ;
Saraf, Laxmikant V. ;
Yang, Zhengguo ;
Liu, Jun .
NANO LETTERS, 2012, 12 (07) :3783-3787
[6]   Electrospun carbon nanofibers as anode materials for sodium ion batteries with excellent cycle performance [J].
Chen, Taiqiang ;
Liu, Yong ;
Pan, Likun ;
Lu, Ting ;
Yao, Yefeng ;
Sun, Zhuo ;
Chua, Daniel H. C. ;
Chen, Qun .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (12) :4117-4121
[7]   Small things make a big difference: binder effects on the performance of Li and Na batteries [J].
Chou, Shu-Lei ;
Pan, Yuede ;
Wang, Jia-Zhao ;
Liu, Hua-Kun ;
Dou, Shi-Xue .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (38) :20347-20359
[8]   Negative electrodes for Na-ion batteries [J].
Dahbi, Mouad ;
Yabuuchi, Naoaki ;
Kubota, Kei ;
Tokiwa, Kazuyasu ;
Komaba, Shinichi .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (29) :15007-15028
[9]   Carbon Nanosheet Frameworks Derived from Peat Moss as High Performance Sodium Ion Battery Anodes [J].
Ding, Jia ;
Wang, Huanlei ;
Li, Zhi ;
Kohandehghan, Alireza ;
Cui, Kai ;
Xu, Zhanwei ;
Zahiri, Beniamin ;
Tan, Xuehai ;
Lotfabad, Elmira Memarzadeh ;
Olsen, Brian C. ;
Mitlin, David .
ACS NANO, 2013, 7 (12) :11004-11015
[10]   Sodium and sodium-ion energy storage batteries [J].
Ellis, Brian L. ;
Nazar, Linda F. .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2012, 16 (04) :168-177