Extraordinarily Persistent Zero Linear Compressibility in Metal-Organic Framework MIL-122(In)

被引:17
作者
Yu, Yishuai [1 ]
Zeng, Qingxin [2 ]
Chen, Yaping [1 ]
Jiang, Lina [1 ]
Wang, Kai [1 ]
Zou, Bo [1 ]
机构
[1] Jilin Univ, Coll Phys, State Key Lab Superhard Mat, Changchun 130012, Peoples R China
[2] Jiangsu Normal Univ, Lab Quantum Mat Design & Applicat, Sch Phys & Elect Engn, Xuzhou 221116, Jiangsu, Peoples R China
来源
ACS MATERIALS LETTERS | 2020年 / 2卷 / 05期
基金
美国国家科学基金会;
关键词
ANISOTROPIC THERMAL-EXPANSION; NEGATIVE AREA COMPRESSIBILITY; PHASE-TRANSITION; RUTILE-TYPE; PRESSURE; DIOXIDE;
D O I
10.1021/acsmaterialslett.0c00090
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Because of its rare linear stability, material with zero linear compression (ZLC) is active in many complicated environments. But it is generally difficult to acquire a single material with ZLC behavior. Herein, we reported a rare ZLC over a huge pressure range (1 atm to 10.5 GPa) in MIL-122(In) material along its a-axis direction. High-pressure angle-dispersive X-ray powder diffraction experiments revealed its structure changes under increasing hydrostatic pressure. Density functional theory calculations confirmed that the ZLC in MIL-122(In) resulted from the unconventional mechanical response of the rhombohedral wine-rack frameworks. Our work provided a new instance of the ZLC material in a large pressure range and demonstrated that the naturally soft materials, metal-organic frameworks, can also exhibit persistent pressure resistance.
引用
收藏
页码:519 / 523
页数:5
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