A highly dl-stereoselective pinacolization of aromatic aldehydes mediated by titanium trichloride in dichloromethane

被引：65

作者：

Clerici, A ^{[1
]}

Clerici, L ^{[1
]}

Porta, O ^{[1
]}

机构：

[1] POLITECN MILAN,DIPARTIMENTO CHIM,I-20133 MILAN,ITALY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 17期

关键词：

D O I：

10.1016/0040-4039(96)00462-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic aldehydes are stereoselectively coupled to dl-hydrobenzoins on treatment with anhydrous TiCl3/CH2Cl2 solution at room temperature. The observed stereochemistry is briefly discussed in term of Ti(IV)-bridging control. (C) 1986 Elsevier Science Ltd.

引用

页码：3035 / 3038

页数：4

共 22 条

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