Adamantyl derivatives of pyrogallol

被引:2
|
作者
Sokolenko, W. A. [1 ]
Svirskaya, N. M. [1 ]
Pavlenko, N. I. [1 ]
Rubailo, A. I. [1 ,2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660049, Russia
[2] Siberian Fed Univ, Krasnoyarsk 660041, Russia
关键词
pyrogallol; adamantan-1-ol; alkylation; trifluoroacetic acid;
D O I
10.1007/s11172-011-0093-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
4-(1-Adamantyl)-, 5-(1-adamantyl)-, and 4,6-bis(1-adamantyl)pyrogallols were obtained by the reaction of adamantan-1-ol with pyrogallol in trifruoroacetic acid. The reaction of pyrogallol with adamantan-1-ol at 200 A degrees C in a solvent-free medium without catalysts resulted in 5-(1-adamantyl)pyrogallol.
引用
收藏
页码:593 / 594
页数:2
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