Synthesis and coordination of 2-acetylimino-1,3-dimethylimidazoline.: The crystal structure of [Cu4I4(C7H11N3O)2]

被引:0
|
作者
Kuhn, N [1 ]
Fawzi, R [1 ]
Grathwohl, M [1 ]
Kotowski, H [1 ]
Steimann, M [1 ]
机构
[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 12期
关键词
copper; imidazoles; chelates; X-ray structure;
D O I
10.1002/(SICI)1521-3749(1998120)624:12<1937::AID-ZAAC1937>3.0.CO;2-L
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
2-Acetylimino-1,3-dimethylimidazoline (2, ImNac) obtained from 1,3-dimethyl-2-iminoimidazoline (1) and acetyl chloride forms with CuI the stepped cubane type complex [Cu4I4(ImNAc)(2)] (3); the X-ray structure of 3 is reported.
引用
收藏
页码:1937 / 1939
页数:3
相关论文
共 50 条
  • [1] Synthesis, crystal structure, and magnetic properties of {[Cu(phen)]2(C4H2O4)2} • 4.5H2O with C4H4O4 = maleic acid
    Zheng, YQ
    Sun, J
    Lin, JL
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (06): : 1397 - 1400
  • [2] Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] • H2O}n
    Tao, RJ
    Li, FA
    Cheng, YX
    Zang, SQ
    Wang, QL
    Niu, JY
    Liao, DZ
    INORGANICA CHIMICA ACTA, 2006, 359 (07) : 2053 - 2058
  • [3] Synthesis and Crystal Structure of a Novel Three-dimensional Cu(II) Compound{[Cu(2,2'-bipy)(C7H4O5S)(H2O)2]·H2O}n
    SU Wei CAO Rong② BI Wen-Hua LI Xing (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2005, (04) : 403 - 406
  • [4] Synthesis and crystal structure of a novel three-dimensional Cu(II) compound {[Cu(2,2′-bipy)(C7H4O5S)(H2O)2]•H2O}n
    Su, W
    Cao, R
    Bi, WH
    Li, X
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (04) : 403 - 406
  • [5] Speciation and transformation in the synthesis of Cu4(im)4(C4O3H6)2(NO2)4(H2O)4 and [(phen)Cu(C2O4)(H2O)]•H2O
    Gong, Yun
    Li, Hui
    Li, Yang Guang
    Wang, Yong Hui
    Tang, Wang
    Hu, Chang Wen
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (01) : 61 - 71
  • [6] Synthesis and crystal structure of [Cu2(NO3)4L2(BIPY)2 (H2O)3]·H2O (L = N,N′-bis(4-pyridylmethyl) isophthalamide
    Susan Buchan
    M. John Plater
    Mark R.St.J. Foreman
    Benjamin M. De Silva
    Janet M.S. Skakle
    Alexandra M.Z. Slawin
    Journal of Chemical Crystallography, 2002, 32 : 5 - 10
  • [7] Syntheses, crystal structures and properties of two Cu(II) coordination polymers:: Cu(C3N2H4)2(HL)2 andCU(C3N2H4)2L with C3N2H4 = imidazole, H2L = adipic acid
    Ying, EB
    Zheng, YQ
    Zhang, HH
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 693 (1-3) : 73 - 80
  • [8] The layered structure of Cu2(H2O)4[C4H4N2][C6H2(COO)4].2H2O
    Köferstein, R
    Robl, C
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (10): : 1756 - 1758
  • [9] Synthesis and crystal structure of [Cu2(NO3)4L2(BIPY)2 (H2O)3]•H2O (L = N,N′-bis(4-pyridylmethyl) isophthalamide
    Buchan, S
    Plater, MJ
    Foreman, MRSJ
    De Silva, BM
    Skakle, JMS
    Slawin, AMZ
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2002, 32 (1-2) : 5 - 10
  • [10] Synthesis and crystal structure of π-complex of copper(I) with 1-allylbenzimidazolium cation [C7H5N2H(C3H5)]+ [Cu3Cl4]−
    E. A. Goreshnik
    D. Schollmeyer
    M. G. Mys’kiv
    Russian Journal of Coordination Chemistry, 2005, 31 : 185 - 189