Study of ferroelectric phase transition in new lead free Ba(Ca1/3Nb2/3)O3 compound

被引:0
作者
Pastor, M. [1 ]
Tirupathi, Patri [2 ]
Kumar, Nawnit [3 ]
Panwar, Amrish K. [4 ]
Chopkar, M. [5 ]
Bhadoria, B. S. [1 ]
机构
[1] Bundelkhand Univ, Dept Phys, Jhansi 284002, Uttar Pradesh, India
[2] Rajiv Gandhi Univ Knowledge Technol AP IIIT, Dept Phys, Rk Valley, India
[3] Indian Inst Technol, Dept Phys, Kharagpur, W Bengal, India
[4] Delhi Technol Univ, Dept Appl Phys, Delhi, India
[5] Natl Inst Technol, Dept Met Engn, Raipur, Chhatisgarh, India
关键词
Sintering; crystal structure; dielectric properties; electrical properties; CERAMICS;
D O I
10.1080/00150193.2017.1360125
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ba(Ca1/3Nb2/3)O-3 (BCN) compound was prepared by solid state reaction route. Structural and electrical analyses were done by X-ray diffraction (XRD), Field effect scanning electron microscope (FESEM), temperature and frequency dependent dielectric and impedance study. Final phase compound shows the formation of single phase cubic crystal system. FESEM micrograph shows the development of the grains in various shapes with different sizes. Relative density of sintered compound found to be 97%. Variation of dielectric constant and dielectric loss with temperature show diffuse ferroelectric characteristics. Electrical ac impedance study reveals that behavior of the electrical resistance and poly dispersive nature of the dielectric relaxation.
引用
收藏
页码:73 / 84
页数:12
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