Discrete Cubane-like Bromide-Water Cluster

被引:41
作者
Bakhoda, Abolghasem [1 ]
Khavasi, Hamid Reza [1 ]
Safari, Nasser [1 ]
机构
[1] Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran
关键词
ORGANIC SUPRAMOLECULAR COMPLEX; HYDROGEN-BOND; (H2O)(12) CLUSTERS; OPEN FRAMEWORK; MOLECULAR ICE; X-RAY; HEXAMER; NETWORK; PLANAR; CRYPTAND;
D O I
10.1021/cg101613b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A well-isolated unique discrete cubane-like dibromide-hexahydrate cluster in the solid phase has been observed as a pyridylphosphine iron(II) counteranion. The bromide-water cluster is stabilized and orderly arranged by hydrogen bonds which display high symmetry.
引用
收藏
页码:933 / 935
页数:3
相关论文
共 52 条
[11]   Structure of a discrete dichloride hexahydrate cube as a tris(diisopropylamino)cyclopropenium salt [J].
Butchard, James R. ;
Curnow, Owen J. ;
Garrett, David J. ;
Maclagan, Robert G. A. R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (45) :7550-7553
[12]   A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4- cluster [J].
Custelcean, R ;
Gorbunova, MG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (47) :16362-16363
[13]   A Metal-Organic Nanotube Exhibiting Reversible Adsorption of (H2O)12 Cluster [J].
Dai, Fangna ;
He, Haiyan ;
Sun, Daofeng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14064-+
[14]   AN UNUSUAL STRUCTURE OF THE HYDRATED SODIUM-CHLORIDE COMPLEX OF CRYPTAND-[2.2.2] [J].
DALLEY, NK ;
KRAKOWIAK, KE ;
BRADSHAW, JS ;
KOU, XL ;
IZATT, RM .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1995, 32 (04) :1201-1204
[15]   Molecular ice with hybrid water-bromide network around a cryptand with a bromide ion included in the cavity to form a host-within-a-host-like structure [J].
Das, Madhab C. ;
Bharadwaj, Parimal K. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (09) :1229-1232
[16]   Supramolecular association of water molecules forming discrete clusters in the voids of coordination polymers [J].
Das, Madhab C. ;
Maity, Shubhra B. ;
Bharadwaj, Parimal K. .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2009, 13 (3-4) :76-90
[17]   Global search for minimum energy (H2O)n clusters, n=3-5 [J].
Day, MB ;
Kirschner, KN ;
Shields, GC .
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (30) :6773-6778
[18]  
Desiraju G. R., 1999, The Weak Hydrogen Bond
[19]   Novel water clusters in the crystalline state: structures of a symmetrical, cyclic hexamer and an 'opened-cube' octamer [J].
Doedens, RJ ;
Yohannes, E ;
Khan, MI .
CHEMICAL COMMUNICATIONS, 2002, (01) :62-63