Discrete Cubane-like Bromide-Water Cluster

被引:41
作者
Bakhoda, Abolghasem [1 ]
Khavasi, Hamid Reza [1 ]
Safari, Nasser [1 ]
机构
[1] Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran
关键词
ORGANIC SUPRAMOLECULAR COMPLEX; HYDROGEN-BOND; (H2O)(12) CLUSTERS; OPEN FRAMEWORK; MOLECULAR ICE; X-RAY; HEXAMER; NETWORK; PLANAR; CRYPTAND;
D O I
10.1021/cg101613b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A well-isolated unique discrete cubane-like dibromide-hexahydrate cluster in the solid phase has been observed as a pyridylphosphine iron(II) counteranion. The bromide-water cluster is stabilized and orderly arranged by hydrogen bonds which display high symmetry.
引用
收藏
页码:933 / 935
页数:3
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