Densities and viscosities of aqueous solutions of 1-propanol and 2-propanol at temperatures from 293.15 K to 333.15 K

被引:267
|
作者
Pang, Fong-Meng
Seng, Chye-Eng [1 ]
Teng, Tjoon-Tow
Ibrahim, M. H.
机构
[1] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia
[2] Univ Sains Malaysia, Sch Ind Technol, George Town 11800, Malaysia
关键词
viscosity; density; 1-propanol; 2-propanol;
D O I
10.1016/j.molliq.2007.01.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Densities and viscosities of the binary aqueous solutions of 1-propanol and 2-propanol have been measured over the whole composition range at temperatures between 293.15 K and 333.15 K. The energies of activation for viscous flow for aqueous solutions of I-propanol and 2-propanol were calculated and found to be 17.94 and 22.16 kJ mol(-1), respectively. A polynomial equation and an equation based on the Power Law and Erying's absolute rate theory were used to correlate the viscosity data of the aqueous solutions of 1-propanol and 2-propanol. The average absolute deviations (AAD) for density correlations of aqueous solutions of 1-propanol and 2-propanol are less than 0.07%. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:71 / 78
页数:8
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