Metal cation-exchanged montmorillonite-catalyzed addition of organic disulfides to alkenes

被引：10

作者：

Nishimura, T ^{[1
]}

Yoshinaka, T ^{[1
]}

Uemura, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2005年 / 78卷 / 06期

关键词：

D O I：

10.1246/bcsj.78.1138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of organic disulfides to alkenes, giving vic-bis(alkylthio)alkanes and vic-bis(arylthio)alkanes, proceeds in chlorobenzene in the presence of a catalytic amount of a variety of metal cation-exchanged montmorillonites (abbreviated as M"(+)-monts), Al3+, Fe3+, Zr4+, and In3+ being effective as M"(+). The most effective Fe3+-mont can be reused for the addition of diphenyl disulfide to cyclohexene at least 8 times without an appreciable loss of catalytic activity.

引用

页码：1138 / 1141

页数：4

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