Three-dimensional photoluminescent pillared metal-organic framework with 4.82 topological channels obtained from the assembly of cadmium(II) acetate and trimellitic salt

被引：60
作者：
Fan, J
Zhu, HF
Okamura, TA
Sun, WY [1 ]
Tang, WX
Ueyama, N
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan
来源：
NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 10期
关键词：
D O I：
10.1039/b304826h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of the piperidinium salt of trimellitic acid (BTC3-) with cadmium(II) acetate dihydrate yields an unprecedented 3D pillared metal-organic framework, [Cd-3(BTC)(2)(H2O)(6)].3H(2)O, showing strong blue luminescence. The framework contains 4.8(2) topological channels, in which the 'floors' are directly connected by the pillars of the BTC3- benzene rings.
引用
收藏
页码：1409 / 1411
页数：3
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