H3N(CH2)3NH3•Zn(HPO3)2 containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids

被引：43

作者：

Harrison, WTA ^{[1
]}

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

来源：

INTERNATIONAL JOURNAL OF INORGANIC MATERIALS | 2001年 / 3卷 / 02期

关键词：

D O I：

10.1016/S1466-6049(01)00014-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solution-mediated synthesis and single-crystal structure of H3N(CH2)(3)NH3. Zn(HPO3)(2) are reported. This phase is built up from chains of vertex-linked ZnO4 and HPO3 building units crosslinked by 1,3-diammonium propane cations. The relationship of the title compound to known zinc phosphate phases is briefly discussed. Crystal data for H3N(CH2)(3)NH3. Zn(HPO3)(2): ZnP2O6N2C3H14, M-r=301.49, ortholhombic, Pbcm (No. 57), a=8.6924 (4) Angstrom, b=7.8926 (4) Angstrom, c=16.6224 (8) Angstrom, V=1140.4 (2) Angstrom (3), Z=4, rho (calc)=1.756 g/cm(3), mu =24.4 cm(-1), T=298 (2) K, R=0.025, R-w=0.037 (calculated w(i)). (C) 2001 Elsevier Science Ltd. AH rights reserved.

引用

页码：187 / 189

页数：3

共 14 条

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