Preparation of Cu2ZnSn(S,Se)4 thin film solar cells by a green and facile solution method

被引:1
作者
Sun, Luanhong [1 ]
Shen, Honglie [1 ]
Shang, Huirong [1 ]
Li, Jinze [1 ]
Wang, Wei [2 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Jiangsu Key Lab Mat & Technol Energy Convers, Nanjing 210016, Jiangsu, Peoples R China
[2] Jinling Inst Technol, Sch Mat Engn, Nanjing 211169, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
CZTSSe solar cell; ethylene glycol; solution method; fine grains layer; GROWTH;
D O I
10.1088/2053-1591/aae19b
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this research, a green and facile solution was reported by using ethylene glycol as solvent into Cu2ZnSn(S,Se)(4) thin films. Highly crystallized CZTSSe thin films without obvious impurity phases were obtained. We found that the carbon chains length of solvent has a notable influence on the of grain size distribution. Comparing the film obtained with 2-methoxyethanol solvent, CZTSSe thin film based on ethylene glycol had a thinner fine grain in the bottom layer and larger grains in the top layer. In addition, the CZTSSe thin film solar cell from ethylene glycol showed an obvious collection ability enhancement and an enhanced conversion efficiency by 45% than that from 2-methoxyethanol.
引用
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页数:5
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共 16 条
[1]   Compound Copper Chalcogenide Nanocrystals [J].
Coughlan, Claudia ;
Ibanez, Maria ;
Dobrozhan, Oleksandr ;
Singh, Ajay ;
Cabot, Andreu ;
Ryan, Kevin M. .
CHEMICAL REVIEWS, 2017, 117 (09) :5865-6109
[2]   Growth and Raman scattering characterization of Cu2ZnSnS4 thin films [J].
Fernandes, P. A. ;
Salome, P. M. P. ;
da Cunha, A. F. .
THIN SOLID FILMS, 2009, 517 (07) :2519-2523
[3]   Tailoring Mo(S,Se)2 structure for high efficient Cu2ZnSn(S,Se)4 solar cells [J].
Gao, Shoushuai ;
Zhang, Yi ;
Ao, Jianping ;
Lin, Shuping ;
Zhang, Zhaojing ;
Li, Xiuling ;
Wang, Donggiao ;
Zhou, Zhiqiang ;
Sun, Guozhong ;
Liu, Fangfang ;
Sun, Yun .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2018, 176 :302-309
[4]   Efficiency Enhancement of Cu2ZnSn(S,Se)4 Solar Cells via Alkali Metals Doping [J].
Hsieh, Yao-Tsung ;
Han, Qifeng ;
Jiang, Chengyang ;
Song, Tze-Bin ;
Chen, Huajun ;
Meng, Lei ;
Zhou, Huanping ;
Yang, Yang .
ADVANCED ENERGY MATERIALS, 2016, 6 (07)
[5]   Earth-Abundant Element Photovoltaics Directly from Soluble Precursors with High Yield Using a Non-Toxic Solvent [J].
Ki, Wooseok ;
Hillhouse, Hugh W. .
ADVANCED ENERGY MATERIALS, 2011, 1 (05) :732-735
[6]   Performance improvement of flexible CZTSSe thin film solar cell by adding a Ge buffer layer [J].
Li, Jinze ;
Shen, Honglie ;
Shang, Huirong ;
Li, Yufang ;
Wu, Wenwen .
MATERIALS LETTERS, 2017, 190 :188-190
[7]   Growth mechanism of Ge-doped CZTSSe thin film by sputtering method and solar cells [J].
Li, Jinze ;
Shen, Honglie ;
Chen, Jieyi ;
Li, Yufang ;
Yang, Jiale .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (41) :28829-28834
[8]   Phase evolution and sintering behaviors of Cu2ZnSnS4 powders synthesized by mechanochemical process with different milling parameters [J].
Liu, Chao-Qian ;
Wen, Bin ;
Wang, Nan ;
Liu, Shi-Min ;
Wang, Hua-Lin ;
Jiang, Wei-Wei ;
Ding, Wan-Yu ;
Xu, Shi-Chong ;
Chai, Wei-Ping .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 708 :428-436
[9]   Growth and characterization of dual ion beam sputtered Cu2ZnSn(S, Se)4 thin films for cost-effective photovoltaic application [J].
Sengar, Brajendra S. ;
Garg, Vivek ;
Awasthi, Vishnu ;
Aaryashree ;
Kumar, Shailendra ;
Mukherjee, C. ;
Gupta, Mukul ;
Mukherjee, Shaibal .
SOLAR ENERGY, 2016, 139 :1-12
[10]   Kesterite-based next generation high performance thin film solar cell: current progress and future prospects [J].
Shi, Zhengqi ;
Attygalle, Dinesh ;
Jayatissa, Ahalapitiya H. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (02) :2290-2306