Dispersive micro-solid phase extraction of 16 priority polycyclic aromatic hydrocarbons from water by using thermally treated clinoptilolite, and their quantification by GC-MS

被引：17

作者：

Ciric, Slobodan ^{[1
]}

Mitic, Violeta ^{[1
]}

Jovanovic, Snezana ^{[1
]}

Ilic, Marija ^{[2
]}

Nikolic, Jelena ^{[1
]}

Stojanovic, Gordana ^{[1
]}

Jovanovic, Vesna Stankov ^{[1
]}

机构：

[1] Univ Nis, Fac Sci & Math, Visegradska 33, Nish 18000, Serbia

[2] Vet Specialized Inst, Lab Sect, Lab Analyt Chem, Dimitrija Tucovica 175, Nish 18106, Serbia

来源：

MICROCHIMICA ACTA | 2018年 / 185卷 / 12期

关键词：

PAHs; D-mu-SPE; Sorbents; Water sample preparation; Natural zeolite; Clinoptilolite; GC-MS; SEM; FTIR; PERFORMANCE LIQUID-CHROMATOGRAPHY; GAS-CHROMATOGRAPHY; MICROEXTRACTION; TETRACYCLINES; OPTIMIZATION; SPECTROMETRY; PESTICIDES; GRAPHENE; SORBENT; TRACE;

D O I：

10.1007/s00604-018-3091-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The authors report on a novel sorbent (thermally treated natural zeolite; clinoptilolite) for use in dispersive micro-solid phase extraction (D-mu-SPE) of polycyclic aromatic hydrocarbons (PAHs) from water samples. The method was applied to the D-mu-SPE of 16 priority PAHs which then were quantified by gas chromatography with mass spectrometric detection (GC-MS). The method was validated in terms of specificity and selectivity, linearity and linear range, accuracy, precision, uncertainty, limits of detection and quantification. Figures of merit include (a) linear analytical ranges between 2.08 and 208 ppb, and (b) detection limits in the range from 0.01 to 0.92 ppb. The method was successfully applied to the determination of PAHs in river waters.

引用

页数：10

共 36 条

[1] Calcium Alginate-Caged Multiwalled Carbon Nanotubes Dispersive Microsolid Phase Extraction Combined With Gas Chromatography-Flame Ionization Detection for the Determination of Polycyclic Aromatic Hydrocarbons in Water Samples [J].

Abboud, Ayad Sami ;

Sanagi, Mohd Marsin ;

Ibrahim, Wan Aini Wan ;

Keyon, Aemi S. Abdul ;

Aboul-Enein, Hassan Y. .

JOURNAL OF CHROMATOGRAPHIC SCIENCE, 2018, 56 (02) :177-186

[2]

Anastassiades M, 2003, J AOAC INT, V86, P412

[3] Dispersive micro-solid-phase extraction of benzodiazepines from biological fluids based on polyaniline/magnetic nanoparticles composite [J].

Asgharinezhad, Ali Akbar ;

Ebrahimzadeh, Homeira ;

Mirbabaei, Fatemeh ;

Mollazadeh, Narges ;

Shekari, Nafiseh .

ANALYTICA CHIMICA ACTA, 2014, 844 :80-89

[4]

Biernat JF, 2000, POL J ENVIRON STUD, V9, P71

[5]

Brito N. M., 2002, Pesticidas - Revista de Ecotoxicologia e Meio Ambiente, V12, P155

[6] Analysis of polycyclic aromatic hydrocarbons in contaminated soil by Curie point pyrolysis coupled to gas chromatography-mass spectrometry, an alternative to conventional methods [J].

Buco, S ;

Moragues, M ;

Doumenq, P ;

Noor, A ;

Mille, G .

JOURNAL OF CHROMATOGRAPHY A, 2004, 1026 (1-2) :223-229

[7]

Castro L. D., 2009, J CHROMATOGR A, V1217, P2383, DOI DOI 10.1016/j.chroma.11.027.

[8]

Celino J.J., 2012, RESOURCES ENV, V2, P141

[9]

Cvetkovic JS, 2016, ANAL METHODS-UK, V8, P1711, DOI [10.1039/C5AY03248B, 10.1039/c5ay03248b]

[10] A novel solid-phase extraction method for separation and preconcentration of zirconium [J].

Faghihian, Hossein ;

Kabiri-Tadi, Mahboobeh .

MICROCHIMICA ACTA, 2010, 168 (1-2) :147-152

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