Self-assembly of a triple-stranded helicate from a rigid di(catechol) ligand and formation of its dimer in the solid state

被引:28
作者
Albrecht, M
Schneider, M
Frohlich, R
机构
[1] Univ Karlsruhe, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
关键词
D O I
10.1039/a803652g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The p-phenylene bridged di(catechol) ligand L-H-4 forms a triple-stranded dinuclear titanium helicate which in the solid state incorporates potassium cations and forms a dimeric species.
引用
收藏
页码:753 / 754
页数:2
相关论文
共 11 条
[1]  
Albrecht, 1996, ANGEW CHEM, V108, P1299
[2]   Racemisation behaviour of trinuclear helicates formed from ethylene-bridged tris(catechol) ligands and titanium(IV) ions [J].
Albrecht, M ;
Schneider, M .
CHEMICAL COMMUNICATIONS, 1998, (01) :137-138
[3]   Stabilization of an unusual coordination geometry at Li+ in the interior of a cryptand-type helicate [J].
Albrecht, M ;
Kotila, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (11) :1208-1210
[4]   FORMATION OF A MESO-HELICATE BY SELF-ASSEMBLY OF 3 BIS(CATECHOLATE) LIGANDS AND 2 TITANIUM(IV) IONS [J].
ALBRECHT, M ;
KOTILA, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (19) :2134-2137
[5]   Alkali-metal cation binding by self-assembled cryptand-type supermolecules [J].
Albrecht, M ;
Rottele, H ;
Burger, P .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (10) :1264-1268
[6]  
Albrecht M., 1995, ANGEW CHEM, V107, P2285
[7]   Generation of an equilibrating collection of circular inorganic copper(I) architectures and solid-state stabilisation of the dicopper helicate component [J].
Baxter, PNW ;
Lehn, JM ;
Rissanen, K .
CHEMICAL COMMUNICATIONS, 1997, (14) :1323-1324
[8]   A tetranuclear meso-helicate [J].
Constable, EC ;
Neuburger, M ;
Whall, LA ;
Zehnder, M .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (03) :219-220
[9]   Dinuclear catecholate helicates: Their inversion mechanism [J].
Kersting, B ;
Meyer, M ;
Powers, RE ;
Raymond, KN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (30) :7221-7222
[10]   Helicates as versatile supramolecular complexes [J].
Piguet, C ;
Bernardinelli, G ;
Hopfgartner, G .
CHEMICAL REVIEWS, 1997, 97 (06) :2005-2062