Supported rhenium sulfide catalysts in thiophene and 4,6-dimethyldibenzothiophene hydrodesulfurization: Effect of acidity of the support over activities

被引：19

作者：

Sepulveda, C. ^{[2
]}

Belliere, V. ^{[1
]}

Laurenti, D. ^{[1
]}

Escalona, N. ^{[2
]}

Garcia, R. ^{[2
]}

Geantet, C. ^{[1
]}

Vrinat, M. ^{[1
]}

机构：

[1] Univ Lyon 1, IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France

[2] Univ Concepcion, Fac Ciencias Quim, Concepcion, Chile

来源：

APPLIED CATALYSIS A-GENERAL | 2011年 / 393卷 / 1-2期

关键词：

Rhenium sulfide; Hydrodesulfurization; Zeolites; Acidity; Support effect; TRANSITION-METAL SULFIDES; HYDROTREATING CATALYSTS; HYDROGENATION PROPERTIES; ZEOLITES; ALKYLDIBENZOTHIOPHENES; DIBENZOTHIOPHENE; SELECTIVITY; REACTIVITY; MECHANISM; SULFUR;

D O I：

10.1016/j.apcata.2010.12.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three different zeolites, gamma-alumina and silica supports were used to prepare ReS2 catalysts by incipient wetness impregnation of ammonium perrhenate (NH4ReO4). The catalysts were characterized and tested in the hydrodesulfurization (HDS) of thiophene in an atmospheric fixed bed reactor, and of the 4,6-dimethyldibenzothiophene (4,6-DMDBT) HDS in a high pressure stirred tank reactor. The results showed that the acidity of the zeolites has a detrimental influence over hydrodesulfurization activity of the Re sulfide, contrarily to the enhancement observed previously with zeolite-supported Mo sulfide catalysts. The catalyst prepared over a non-acidic zeolite (HSZ-390) was found very efficient in thiophene HDS and comparable to silica for 4,6-DMDBT. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：288 / 293

页数：6

共 50 条

[1] Hydrodesulfurization of 4,6-dimethyldibenzothiophene over NiMo supported on Ga-modified Y zeolites catalysts
Zhou, Wenwu
Zhou, Anning
Zhang, Yating
Zhang, Cuicui
Chen, Zhiping
Liu, Lang
Zhou, Yasong
Wei, Qiang
Tao, Xiujuan
JOURNAL OF CATALYSIS, 2019, 374 : 345 - 359
[2] Hydrodesulfurization of 4,6-Dimethyldibenzothiophene over Noble Metals Supported on Mesoporous Zeolites
Sun, Yinyong
Prins, Roel
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) : 8478 - 8481
[3] Hydrodesulfurization of 4,6-Dimethyldibenzothiophene over CoMo Catalysts Supported on γ-Alumina with Different Morphology
Li, Xuehui
Chai, Yongming
Liu, Bin
Liu, Huan
Li, Jingfeng
Zhao, Ruiyu
Liu, Chenguang
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (23) : 9665 - 9673
[4] Preparation of Unsupported NiMoP Catalysts for 4,6-Dimethyldibenzothiophene Hydrodesulfurization
Wang, Rui
Smith, Kevin J.
CATALYSIS LETTERS, 2014, 144 (09) : 1594 - 1601
[5] Hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene over NiMo and CoMo sulfide catalysts: Kinetic modeling approach for estimating selectivity
Farag, Hamdy
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 348 (01) : 219 - 226
[6] Performance of CoMoS catalysts supported on nanoporous carbon in the hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene
Lee, JJ
Han, S
Kim, H
Koh, JH
Hyeon, T
Moon, SH
CATALYSIS TODAY, 2003, 86 (1-4) : 141 - 149
[7] Hydrodesulfurization of 4,6-dimethyldibenzothiophene over NiMo sulfide catalysts supported on meso-microporous Y zeolite with different mesopore sizes
Zhou, Wenwu
Wei, Qiang
Zhou, Yasong
Liu, Meifang
Ding, Sijia
Yang, Qi
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 238 : 212 - 224
[8] Hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene over NiMo supported on yolk-shell silica catalysts with adjustable shell thickness and yolk size
Yu, Ke
Kong, Weimin
Zhao, Zhen
Duan, Aijun
Kong, Lian
Wang, Xilong
JOURNAL OF CATALYSIS, 2022, 410 : 128 - 143
[9] Catalytic Hydrodesulfurization of Thiophene, Dibenzothiophene and 4,6-Dimethyldibenzothiophene on a CoMoS Catalyst
Prabhu, M. K.
Louwen, J. N.
Vogt, E. T. C.
Groot, I. M. N.
CATALYSIS LETTERS, 2025, 155 (03)
[10] Preparation of Unsupported NiMoP Catalysts for 4,6-Dimethyldibenzothiophene Hydrodesulfurization
Rui Wang
Kevin J. Smith
Catalysis Letters, 2014, 144 : 1594 - 1601

← 1 2 3 4 5 →