mechanochemistry;
mechanical activation;
chemo-mechanochemical effect;
feedback in solid-state processes;
mechanochemical activation as a result of the reaction itself;
reactivity of solids;
SOLID-STATE REACTIONS;
THERMAL-DECOMPOSITION;
INTERCALATION COMPOUNDS;
POTASSIUM-PERMANGANATE;
AMMONIUM-PERCHLORATE;
STATIONARY FRONT;
STRESS EVOLUTION;
DRIFT KINETICS;
LITHIUM-SALTS;
LOCAL STRESS;
D O I:
10.1007/s11172-018-2162-z
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The review addresses the special case of mechanical activation of solid-state chemical reactions when the stress field, strain, and defects in crystals are induced by the chemical reaction itself rather than by the external mechanical impact (chemo-mechanochemical (CMC) effect). This review presents the analysis and state-of-the-art of research activities in this area. Different cases of the CMC effect in homogeneous and heterogeneous systems are considered: with or without changes in the chemical composition, with or without formation of solid products, etc.