Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect

被引:15
|
作者
Boldyrev, V. V. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochem, 18 Ul Kutateladze, Novosibirsk 630128, Russia
关键词
mechanochemistry; mechanical activation; chemo-mechanochemical effect; feedback in solid-state processes; mechanochemical activation as a result of the reaction itself; reactivity of solids; SOLID-STATE REACTIONS; THERMAL-DECOMPOSITION; INTERCALATION COMPOUNDS; POTASSIUM-PERMANGANATE; AMMONIUM-PERCHLORATE; STATIONARY FRONT; STRESS EVOLUTION; DRIFT KINETICS; LITHIUM-SALTS; LOCAL STRESS;
D O I
10.1007/s11172-018-2162-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The review addresses the special case of mechanical activation of solid-state chemical reactions when the stress field, strain, and defects in crystals are induced by the chemical reaction itself rather than by the external mechanical impact (chemo-mechanochemical (CMC) effect). This review presents the analysis and state-of-the-art of research activities in this area. Different cases of the CMC effect in homogeneous and heterogeneous systems are considered: with or without changes in the chemical composition, with or without formation of solid products, etc.
引用
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页码:933 / 948
页数:16
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