Future generations of cathode materials: an automotive industry perspective

被引:691
作者
Andre, Dave [1 ]
Kim, Sung-Jin [1 ]
Lamp, Peter [1 ]
Lux, Simon Franz [2 ]
Maglia, Filippo [1 ]
Paschos, Odysseas [1 ]
Stiaszny, Barbara [1 ]
机构
[1] BMW Grp, D-80788 Munich, Germany
[2] BMW Grp Technol Off USA, Mountain View, CA 94043 USA
关键词
LITHIUM-ION BATTERIES; ENHANCED ELECTROCHEMICAL PERFORMANCE; POSITIVE-ELECTRODE MATERIALS; EXCELLENT CYCLE PERFORMANCE; VOLTAGE SPINEL CATHODES; LI-ION; THERMAL-STABILITY; ENERGY-STORAGE; VANADIUM FLUOROPHOSPHATE; HYDROTHERMAL SYNTHESIS;
D O I
10.1039/c5ta00361j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Future generations of electrified vehicles require driving ranges of at least 300 miles to successfully penetrate the mass consumer market. A significant improvement in the energy density of lithium batteries is mandatory, maintaining at the same time similar, or improved, rate capability, lifetime, cost, and safety. Several new cathode materials have been claimed over the last decade to allow for this energy improvement. The possibility that some of them will find application in the future automotive batteries is critically evaluated here by first considering their theoretical and experimentally demonstrated energy densities at the material level. For selected candidates, the energy density at the automotive battery cell level for electric vehicle applications is calculated using an in-house developed software. For the selected cathodes, literature results concerning their power capability and lifetime are also discussed with reference to the automotive targets.
引用
收藏
页码:6709 / 6732
页数:24
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