Viscosities of binary mixtures of isomeric butanols or isomeric chlorobutanes with 2-methyltetrahydrofuran

被引:24
作者
Giner, B [1 ]
Aldea, ME [1 ]
Martín, S [1 ]
Gascón, I [1 ]
Lafuente, C [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ Quim Fis, E-50009 Zaragoza, Spain
关键词
D O I
10.1021/je030167i
中图分类号
O414.1 [热力学];
学科分类号
摘要
Viscosities for the binary mixtures of isomeric butanols or isomeric chlorobutanes with 2-methyltetrahydrofuran were determined at the temperatures 298.15 K and 313.15 K; the viscosities of the mixture of 2-methyl-2-chloropropane with 2-methyltetrahydrofuran were measured only at 298.15 K. The viscosity data were correlated by the McAllister equation. Viscosity deviations for the mixtures containing isomeric butanols are negative over the whole composition range. On the other hand, for the mixtures involving isomeric chlorobutanes, viscosity deviations are slightly negative, except for that for 1-chlorobutane; in this case viscosity deviations present an inversion of sign.
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页码:1296 / 1300
页数:5
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