Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II)

被引：0
|
作者：
Dey, S
Jain, VK [1 ]
Knoedler, A
Kaim, W
机构：
[1] Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
[2] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2003年 / 42卷 / 09期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of Na2PdCl4 with Me2NCH2CH2SH.HCl in methanol affords a trimeric complex [PdCl(SCH2CH2NMe2)](3). Treatment of [M2Cl2(mu-Cl)(2)(PR3)(2)] (M = Pd or Pt) with Me2NCH2CH2SH.HCl in the presence of NaHCO3 Yields complexes of the type [MCl(SCH2CH2NMe2)(PR3)](n) (n = 1 or 2). These complexes have been isolated as monomeric species containing chelating thiolate ligands. In some cases, with more basic phosphines, binuclear complexes (n = 2) containing bridging thiolate ligands are also formed. All complexes have been characterized by elemental analysis and NMR spectroscopy. The structure of [PdCl(SCH2CH2NMe2)(PPh3)] (2c) has been established by X-ray crystallography.
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页码：2339 / 2343
页数：5
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