Chlorine-35 NQR study of a structural phase transition in (ND4)2PdCl6

被引：4

作者：

Kume, Y

Asaji, T

机构：

[1] Azabu Univ, Coll Environm Hlth, Dept Basic Sci, Sagamihara, Kanagawa 229, Japan

[2] Azabu Univ, Biosci Res Inst, Sagamihara, Kanagawa 229, Japan

[3] Nihon Univ, Coll Humanities & Sci, Dept Chem, Setagaya Ku, Tokyo 156, Japan

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 1998年 / 53卷 / 6-7期

关键词：

isotope effect; phase transition; chlorine NQR; spin-lattice relaxation; deuterated ammonium hexachloropalladate;

D O I：

10.1515/zna-1998-6-738

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

dependences of (SCl)-S-35 NQR frequencies and spin-lattice relaxation times were measured at 4.2 to 400 K for natural and deuterated ammonium hexaohloropalladate. It was confirmed that only the deuterated salt undergoes a first order phase transition at 30 K. The crystal structure of the low-temperarure phase is predicted to be the same as that of the deuterated ammonium hexachloroplatinate and hexachloroplumbate. The mechanism of the deuteration-induced phase transition is discussed.

引用

页码：514 / 517

页数：4

共 50 条

[21] Deuteron NMR study of ammonium ion mobility near the order-disorder phase transition in (ND4)2PbCl6
Filipek, P
Lalowicz, ZT
Olejniczak, Z
Birczynski, A
CHEMICAL PHYSICS LETTERS, 2003, 367 (1-2) : 55 - 61
[22] NQR-NMR AND RAMAN-STUDY OF A STRUCTURAL PHASE-TRANSITION IN (NH4)2PBCL6
DIMITROPOULOS, C
PELZL, J
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1989, 44 (02): : 109 - 116
[23] Structural dynamics in (ND4)2[Cu(D2O)6](SO4)2
Masters, VM
Riley, MJ
Hitchman, MA
INORGANIC CHEMISTRY, 2001, 40 (05) : 843 - 849
[24] Deuteron NMR relaxation, spectra, and evidence for the order-disorder phase transition in (ND4)2PtCl6
Birczynski, A.
Ylinen, E. E.
Punkkinen, M.
Prager, M.
Szymocha, A. M.
Lalowicz, Z. T.
JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (18):
[25] The phase transition of (ND4)3D(SO4)2 studied with Raman scattering
Kasahara, M
Yagi, T
FERROELECTRICS, 2002, 266 : 131 - 137
[26] The phase transition of (ND4)3D(SO4) 2 studied with Raman scattering
Kasahara, M.
Yagi, T.
Ferroelectrics, 2002, 266 : 467 - 473
[27] Crystal structure and a new phase transition of (ND4)(3)D(SO4)(2) in high temperature phase
Fukami, T
Ninomiya, H
Chen, RH
SOLID STATE IONICS, 1997, 98 (1-2) : 105 - 111
[28] Photopyroelectric (PPE) and acoustic emission (AE) investigation of structural phase transition at low temperature in (ND4)(2)TeCl6 and (NH4)HSO4 crystals
Chirtoc, M
Giese, D
Arnscheidt, B
Pelzi, J
PROGRESS IN NATURAL SCIENCE, 1996, 6 : S258 - S261
[29] NMR-STUDY OF HINDERED ROTATION IN SOLID (ND4)2GEF6
TUOHI, JE
YLINEN, EE
NIEMELA, LKE
CHEMICAL PHYSICS LETTERS, 1974, 28 (01) : 35 - 38
[30] A pulsed Cl-35 NQR study on the molecular motions and phase transition of 4-chlorobenzyl alcohol
Niki, H
Kano, K
Hashimoto, M
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1996, 51 (5-6): : 731 - 735

← 1 2 3 4 5 →