Synthesis and crystal structure of bis-[(4S,5S)-4,5-dihydro-4,5-diphenyl-2-(2′-oxidophenyl-χO)oxazole-χN] copper(II) and its application in the asymmetric Baeyer-Villiger reaction

被引：35

作者：

Peng, YG

Feng, XM ^{[1
]}

Yu, KB

Li, Z

Jiang, YZ

Yeung, CH

机构：

[1] Sichuan Univ, Fac Chem, Chengdu 610064, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

[3] Hong Kong Polytech Univ, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China

[4] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 619卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

asymmetric catalysis; crystal structure; chiral oxazoline; Baeyer-Villiger reaction;

D O I：

10.1016/S0022-328X(00)00687-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new oxazolines (3 and 4) and their copper complexes (5 and 6) were synthesized. The four compounds were characterized by elemental analysis and H-1-NMR, IR, MS spectrometry. The molecular structure of compound 6 was determined by single-crystal X-ray diffraction analysis. The four coordinate atoms [N(1), N(2), O(2), O(4)] and the central metal atom (Cu) form a saddle configuration. Compounds 5 and 6 were found to be moderately effective in the catalytic asymmetric Baeyer-Villiger reaction of 2-phenylcyclohexanone. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：204 / 208

页数：5

共 43 条

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[37] Synthesis, crystal structure, and spectroscopic characterization of trans-Bis[(μ-1,3-bis(4-pyridyl)propane)(μ-(3-thiopheneacetate-O))(3-thiopheneacetate-O))-dicopper(II), {[Cu2(O2CCH2C4H3S)4μ-(BPP)2]}n:: From a dinuclear paddle-wheel copper(II) unit to a 2-D coordination polymer involving monatomic carboxylate bridges
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[38] Crystal structure of [1-(4-carboxyphenyl)-5-mercapto-1H-tetrazole]-bis(1,10-phenanthroline)copper(II) perchlorate - methanol (1:1.5), [Cu(C8H5N4O2S)(C12H8N2)2][ClO4] • 1.5CH3OH
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