Crystalline structure of poly(hexamethylene succinate) and single crystal degradation studies

The morphology of solution grown single crystals of poly(hexamethylene succinate) (PE 6 4) was investigated using dilute alcohol or diol solutions by isothermal crystallization. Increasing temperatures changed the morphology of truncated rhombic crystals, which became lenticular crystals. Spiral growths and multilayered crystals as well as characteristic striations which mainly form in the {110} sectors were often observed. A regular folding surface was found by using polyethylene decoration techniques. Lamellar crystals were easily degraded with different lipases. A preferential enzymatic attack was observed to occur on the crystal edges, giving rise in some cases to highly irregular borders with a fringed texture. Lamellae gave rise to well resolved electron diffraction patterns that allowed the main packing characteristics to be determined. Fiber X-ray diffraction patterns indicate a quasi planar zig-zag conformation and a large unit cell containing eight molecular segments. This cell could not be deduced from the typical hk0 electron diffraction pattern but could be assessed from the patterns of tilted specimens. Simulation of electron diffraction patterns indicates that molecular segments are arranged with setting angles close to +/- 46 degrees or +/- 226 degrees. In addition, neighbouring chains along both a- and b-axis have setting angles differing by 180 degrees in order to justify the deduced cell dimensions. (c) 2007 Elsevier Ltd. All rights reserved.