Synthesis of Si3N4 by the carbo-thermal reduction and nitridation of diatomite

被引：93
作者：
Arik, H [1 ]
机构：
[1] Gazi Univ, Dept Met, Fac Tech Educ, TR-06500 Ankara, Turkey
来源：
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2003年 / 23卷 / 12期
关键词：
carbothermal reduction; diatomite; nitridation; Si3N4;
D O I：
10.1016/S0955-2219(03)00038-4
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A study was undertaken to production Of Si3N4 Powders by carbo-thermal reduction and nitridation (CTRN) of diatomite. Test samples were prepared by mixing 99% purity and mean powder size of 2.4 mum of carbon black and maximum particle size of 150 mum diatomite with C/SiO2 molar ratio 4. Prepared sample was subjected to CTRN process at temperatures of 1300, 1350, 1400, and 1450 degreesC for 4. 8, and 16 h. CTRN process was conducted in an atmosphere controlled tube furnace in nitrogen flow 5 cm(3)/min. All products were examined by XRD and SEM-EDX to determine the transformation, morphology and chemical composition. The results showed that the best Si3N4 transformation occurred at 1400 degreesC for 16 h. (C) 2003 Elsevier Science Ltd. All rights reserved.
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页码：2005 / 2014
页数：10
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