Two-step hydrothermal conversion of Pubescens to obtain furans and phenol compounds separately

被引:26
|
作者
Luo, Jia [1 ]
Xu, Yong [1 ]
Zhao, Lingjie [1 ]
Dong, Linlin [1 ]
Tong, Dongmei [1 ]
Zhu, Liangfang [1 ]
Hu, Changwei [1 ]
机构
[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China
基金
高等学校博士学科点专项科研基金;
关键词
Pubescens; Hydrothermal conversion; Two-step process; Furans; Phenols; HOT-COMPRESSED WATER; SUPERCRITICAL WATER; CATALYTIC HYDRODEOXYGENATION; DIRECT LIQUEFACTION; BIOMASS CONVERSION; HIGH-TEMPERATURE; PYROLYSIS; LIGNIN; DECOMPOSITION; HYDROLYSIS;
D O I
10.1016/j.biortech.2010.06.097
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The stepwise hydrothermal conversion of Pubescens selectively to furans and phenol compounds was investigated in a sealed autoclave reactor. The influence of reaction temperature and reaction time on the product distribution was studied. The results were compared to those from direct pyrolysis process. The residues from Pubescens via hydrothermal route and pyrolytic route were characterized by SEM and component analysis. A new method for obtaining furans and phenols separately through a two-step process was proposed. The first step was suggested performing at a moderate temperature for a shorter time to obtain liquid product with high furan content, while the second step was designed proceeding at a higher temperature for a comparatively longer time to produce more phenol compounds. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8873 / 8880
页数:8
相关论文
共 38 条
  • [1] A Simple Two-Step Method for the Selective Conversion of Hemicellulose in Pubescens to Furfural
    Luo, Yiping
    Li, Zheng
    Zuo, Yini
    Su, Zhishan
    Hu, Changwei
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (09): : 8137 - 8147
  • [2] Two-step thermal conversion of oleaginous microalgae into renewable hydrocarbons
    Espinosa-Gonzalez, Isabel
    Asomaning, Justice
    Mussone, Paolo
    Bressler, David C.
    BIORESOURCE TECHNOLOGY, 2014, 158 : 91 - 97
  • [3] Two-step catalytic conversion of lignocellulose to alkanes
    Sun, Zhuohua
    Buwalda, Daniel
    Barta, Katalin
    RSC ADVANCES, 2019, 9 (41) : 23727 - 23734
  • [4] Two-step hydrogen transfer catalysis conversion of lignin to valuable small molecular compounds
    Li, Zhihao
    Bi, Zhihao
    Yan, Lifeng
    GREEN PROCESSING AND SYNTHESIS, 2017, 6 (04) : 363 - 370
  • [5] Conversion of ethanol fermentation stillage into aliphatic ketones by two-step process of hydrothermal treatment and catalytic reaction
    Mansur, Dieni
    Shimokawa, Mana
    Oba, Kiyoshi
    Nakasaka, Yuta
    Tago, Teruoki
    Masuda, Takao
    FUEL PROCESSING TECHNOLOGY, 2013, 108 : 139 - 145
  • [6] Improved two-step hydrothermal process for acetic acid production from carbohydrate biomass
    Huo, Zhibao
    Fang, Yan
    Yao, Guodong
    Zeng, Xu
    Ren, Dezhang
    Jin, Fangming
    JOURNAL OF ENERGY CHEMISTRY, 2015, 24 (02) : 207 - 212
  • [7] Microbial hydrogen production from phenol in a two-step biological process
    Shi, Xian-Yang
    Li, Wen-Wei
    Yu, Han-Qing
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (37) : 12627 - 12633
  • [8] Two-step conversion of cellulose to levoglucosenone using updraft fixed bed pyrolyzer and catalytic reformer
    Huang, Xin
    Kudo, Shinji
    Hayashi, Jun-ichiro
    FUEL PROCESSING TECHNOLOGY, 2019, 191 : 29 - 35
  • [9] Study on two-step hydrothermal liquefaction of macroalgae for improving bio-oil
    Wang, Shuang
    Zhao, Shuang
    Cheng, Xiaoxue
    Qian, Lili
    Barati, Bahram
    Gong, Xun
    Cao, Bin
    Yuan, Chuan
    BIORESOURCE TECHNOLOGY, 2021, 319
  • [10] Two-step Conversion of Acetic Acid to Bioethanol by Ethyl Esterification and Catalytic Hydrogenolysis
    Phaiboonsilpa, Natthanon
    Kawamoto, Haruo
    Minami, Eiji
    Masuda, Shouzo
    Wakagi, Ryota
    Sunayama, Takayuki
    Saka, Shiro
    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2020, 63 (04) : 196 - 203