Lipase-ultrasound assisted synthesis of polyesters

被引：24
作者：
Tomke, Prerana D. [1 ,2 ]
Zhao, Xiaoman [1 ,3 ,4 ]
Chiplunkar, Pranali P. [1 ,5 ]
Xu, Bo [1 ]
Wang, Hongbo [3 ,4 ]
Silva, Carla [6 ]
Rathod, Virendra K. [2 ]
Cavaco-Paulo, Artur [1 ,6 ]
机构：
[1] Jiangnan Univ, Int Joint Res Lab Text & Fiber Bioproc, Wuxi 214122, Peoples R China
[2] Inst Chem Technol, Dept Chem Engn, Bombay 400019, Maharashtra, India
[3] Jiangnan Univ, Jiangsu Engn Technol Res Ctr Funct Text, Wuxi 214122, Peoples R China
[4] Jiangnan Univ, Key Lab Sci & Technol Ecotext, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China
[5] Inst Chem Technol, Dept Oils Oleochem & Surfactants Technol, Bombay 400019, Maharashtra, India
[6] Univ Minho, Ctr Biol Engn, Campus Gualtar, P-4710057 Braga, Portugal
来源：
ULTRASONICS SONOCHEMISTRY | 2017年 / 38卷
关键词：
Ultrasound; Lipase; Polyester; PET polymeric beads; CATALYZED SYNTHESIS; ACOUSTIC CAVITATION; ACTIVATED CARBON; EXTRACTION; REMOVAL; ACETATE; ENZYME; PET;
D O I：
10.1016/j.ultsonch.2017.03.051
中图分类号：
O42 [声学];
学科分类号：
070206 ; 082403 ;
摘要：
Poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), were enzymatically synthesized by immobilized Candida antarctica lipase B in solvent free conditions. The synthesis of these polyesters was based on the ester-ester exchange reaction between ethylene glycol diacetate and di-ethyl glutarate, di-benzyl malonate, di-n-octyl phthalate to produce poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), respectively. The effect of ultrasound and PET polymeric beads was evaluated and showed to improve the synthesis of all polyesters. Ultrasound, as a green solvent-free technology, showed high potentiality for the polyester synthesis intensification.
引用
收藏
页码：496 / 502
页数：7
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