Beckmann rearrangement of cyclohexanone oxime over Hβ zeolite and Hβ zeolite-supported boride

被引：32

作者：

Zhang, YJ

Wang, YQ ^{[1
]}

Bu, YF

Mi, ZT

Wu, W

Min, E

Han, S

Fu, SB

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China

[2] SINOPEC, Res Inst Petr Proc, Beijing 100083, Peoples R China

[3] Yingshan Petrochem Plant, Res Inst, Yueyang 414003, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2005年 / 6卷 / 01期

关键词：

H beta zeolite; H beta zeolite-supported boride; cyclohexanone oxime; Beckmann rearrangement;

D O I：

10.1016/j.catcom.2004.10.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ho was synthesized by a hydrothermal method followed by ion exchange and used as support for the preparation of a Hbeta zeolite-supported boride by impregnating H3BO3. The two catalysts were characterized by BET surface area measurement, XRD, IR, pyridine-TPD, etc. and studied in the Beckmann rearrangement of cyclohexanone oxime. In comparison with pure Hbeta, the loadings of 9.09 wt% B2O3 lead to lower BET area, more total acid sites, more weak acid sites, especially more weak Bronsted acid sites, and slow deactivation in the Beckmann rearrangement. The results indicated that for the catalysts having the structure of beta zeolite, the suitable acid sites for the Beckmann rearrangement might be weak Bronsted acid. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：53 / 56

页数：4

共 50 条

[41] Two-Phase Beckmann Rearrangement of Cyclohexanone Oxime under Milder Conditions in Cyclohexane
Liu, Guoqing
Wu, Jian
Luo, He'an
ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5, 2013, 634-638 : 145 - 151
[42] Active sites of a [B]-ZSM-5 zeolite catalyst for the Beckmann rearrangement of cyclohexanone grime to caprolactam
Heitmann, GP
Dahlhoff, G
Niederer, JPM
Hölderich, WF
JOURNAL OF CATALYSIS, 2000, 194 (01) : 122 - 129
[43] Silicalite-1 deactivation in vapour phase Beckmann rearrangement of cyclohexanone oxime to caprolactam
Cesana, Alberto
Palmery, Stefano
Buzzoni, Roberto
Spano, Guido
Rivetti, Franco
Carnelli, Lino
CATALYSIS TODAY, 2010, 154 (3-4) : 264 - 270
[44] Beckmann Rearrangement of Cyclohexanone Oxime to ε-Caprolactam in a Modified Catalytic System of Trifluoroacetic Acid
Zhang, J. S.
Riaud, A.
Wang, K.
Lu, Y. C.
Luo, G. S.
CATALYSIS LETTERS, 2014, 144 (01) : 151 - 157
[45] Beckmann rearrangement of cyclohexanone oxime over mesoporous Si-MCM-41 and Al-MCM-41 molecular sieves
Chaudhari, K
Bal, R
Chandwadkar, AJ
Sivasanker, S
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 177 (02) : 247 - 253
[46] Estimation of kinetics parameters in Beckmann rearrangement of cyclohexanone oxime using genetic algorithm
Jian Wu
Zhong Li
He-an Luo
Journal of Central South University of Technology, 2006, 13 : 383 - 388
[47] Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam using mesoporous molecular sieves ALSBA-15
Chang, JC
Ko, AN
REACTION KINETICS AND CATALYSIS LETTERS, 2004, 83 (02): : 283 - 290
[48] On the mechanism of the organocatalyzed Beckmann rearrangement of cyclohexanone oxime by trifluoroacetic acid in aprotic solvent
Ronchin, L.
Vavasori, A.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 313 (1-2) : 22 - 30
[49] The use of MCM-22 as catalyst for the Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam
Dahlhoff, G
Barsnick, U
Hölderich, WF
APPLIED CATALYSIS A-GENERAL, 2001, 210 (1-2) : 83 - 95
[50] Estimation of kinetics parameters in Beckmann rearrangement of cyclohexanone oxime using genetic algorithm
吴剑
李忠
罗和安
Journal of Central South University of Technology(English Edition), 2006, (04) : 383 - 388

← 1 2 3 4 5 →