Advances in the synthesis and catalysis of solid and hollow zeolite-encapsulated metal catalysts

被引：19
作者：
Dai, Chengyi [1 ,2 ]
Zhang, Anfeng [2 ]
Song, Chunshan [2 ,3 ,4 ]
Guo, Xinwen [2 ]
机构：
[1] Northwest Univ, Collaborat Innovat Ctr Dev Energy & Chem Ind Nort, Shaanxi Res Ctr Engn Technol Clean Coal Convers, Int Sci & Technol Cooperat Base Clean Utilizat Hy, Xian, Shaanxi, Peoples R China
[2] Dalian Univ Technol, PSU DUT Joint Ctr Energy Res, Sch Chem Engn, State Key Lab Fine Chem, Dalian, Peoples R China
[3] Penn State Univ, Dept Energy & Mineral Engn, PSU DUT Joint Ctr Energy Res, EMS Energy Inst, University Pk, PA 16802 USA
[4] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA
来源：
ADVANCES IN CATALYSIS, VOL 63 | 2018年 / 63卷
关键词：
SIZE-SELECTIVE HYDROGENATION; SCHIFF-BASE COMPLEXES; PLATINUM NANOPARTICLES; SILICALITE-1; ZEOLITE; PHYSICOCHEMICAL PROPERTIES; PRODUCT SELECTIVITY; HIGHLY EFFICIENT; SINGLE-CRYSTALS; OXIDATION; CLUSTERS;
D O I：
10.1016/bs.acat.2018.10.002
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metals and zeolites are two important types of catalysts and widely used in oxidation-reduction and acid-catalyzed reactions, respectively. In recent years, zeolite-encapsulated metal catalysts have attracted great interest due to their excellent performance in metal-acid synergistic catalysis, selectivity to desired product, anti-leaching, and anti-sintering of metal. This review highlights the synthesis strategies for solid and hollow zeolite-encapsulated metal catalysts, such as ion-exchange, "ship-in-a-bottle," hydrothermal crystallization, dry gel conversion, and posttreatment method, and their activity, selectivity, and stability in different reactions including hydrogenation, oxidation, reforming, coupling, reforming, hydroxylation, and degradation. The synthesis and advantages of hollow zeolite-encapsulated metal catalysts in various reactions are highlighted.
引用
收藏
页码：75 / 115
页数：41
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