Recent advances in hydrogen-bonded hexameric encapsulation complexes

被引：146

作者：

Avram, Liat ^{[1
]}

Cohen, Yoram ^{[1
]}

Rebek, Julius, Jr. ^{[2
,3
]}

机构：

[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

[3] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 19期

关键词：

MOLECULAR CAPSULES; DIFFUSION NMR; REVERSIBLE ENCAPSULATION; RESORCINARENE CAPSULES; GUEST MOLECULES; WATER-MOLECULES; PYROGALLOLARENE; SPECTROSCOPY; RECOGNITION; STABILITY;

D O I：

10.1039/c1cc10150a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Basic research in the chemistry of hexameric resorcin[4]arenes and pyrogallol[4] arenes during the last decade is reviewed. Applications of NMR methods to determine solution structures, host guest properties and exchange dynamics are discussed. The scientific issue is the behavior of molecules in small spaces; the challenge is to translate this information to practical applications in, say, catalysis or transport.

引用

页码：5368 / 5375

页数：8

共 70 条

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