Effect of Some Process Parameters on the Main Properties of Activated Carbon Produced from Peat in a Lab-Scale Process

被引:62
作者
Bergna, D. [1 ,2 ]
Hu, T. [1 ]
Prokkola, H. [1 ]
Romar, H. [1 ,2 ]
Lassi, U. [1 ,2 ]
机构
[1] Univ Oulu, Res Unit Sustainable Chem, POB 3000, Oulu 90014, Finland
[2] Univ Jyvaskyla, Unit Appl Chem, Kokkola Univ Consortium Chydenius, Talonpojankatu 2B, Kokkola 67100, Finland
关键词
Activated carbon; Peat; DOE; Pore size distribution; MODDE; ADSORPTION; HYDROGEN; DIOXIDE; BIOMASS; OPTIMIZATION; PRECURSORS; SUPPORTS; CATALYST; METALS; SHELLS;
D O I
10.1007/s12649-019-00584-2
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Activated carbons (ACs) are widely used in different industrial processes as adsorbents for pollutant removal or as catalytic material support. The parameters and methods of activation can vary, and they affect the final characteristics of ACs, e.g., specific surface area, pore size distribution, and surface functional groups. The results of this study show that microporosity and mesoporosity can be modified, variating these parameters. ACs from Northern Finland Region peat have been prepared through physical activation with steam. The process has been evaluated using the design of experiment approach. Different parameters have been considered as factors, including holding time, oven temperature, heating rate, steam flow, nitrogen flow, kiln rotation, and biomass initial mass. Based on these factors, several responses characterizing the porosity and the elemental analysis of ACs have been selected. All the data collected have been processed statistically using the Fractional Factorial Resolution IV design linear model in a screening configuration fitted with a partial least squares regression using MODDE 9.1 by Umetrics Software. [GRAPHICS] .
引用
收藏
页码:2837 / 2848
页数:12
相关论文
共 54 条
[31]  
Marsh H, 2006, ACTIVATED CARBON, P243, DOI 10.1016/B978-008044463-5/50019-4
[32]  
Marsh H, 2006, ACTIVATED CARBON, P322, DOI 10.1016/B978-008044463-5/50020-0
[33]  
Marsh H, 2006, ACTIVATED CARBON, P1
[34]   Activated Carbon from Rubber Wood Sawdust by Carbon Dioxide Activation [J].
Mazlan, Mohammad Amir Firdaus ;
Uemura, Yoshimitsu ;
Yusup, Suzana ;
Elhassan, Fathelrahman ;
Uddin, Azhar ;
Hiwada, Ai ;
Demiya, Mitsutaka .
PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 :530-537
[35]  
Montgomery D.C., 2014, DESIGN EXPT SEVERAL
[36]   Synthesis of activated carbon from lignocellulosic biomass and its applications in air pollution control-a review [J].
Nor, Norhusna Mohamad ;
Chung, Lau Lee ;
Teong, Lee Keat ;
Mohamed, Abdul Rahman .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2013, 1 (04) :658-666
[37]  
Oubagaranadin JUK, 2011, ACTIVATED CARBON CLA
[38]   Carbons from second generation biomass as sustainable supports for catalytic systems [J].
Prati, Laura ;
Bergna, Davide ;
Villa, Alberto ;
Spontoni, Paolo ;
Bianchi, Claudia L. ;
Hu, Tao ;
Romar, Henrik ;
Lassi, Ulla .
CATALYSIS TODAY, 2018, 301 :239-243
[39]   THE USE OF STEAM AND CO2 AS ACTIVATING AGENTS IN THE PREPARATION OF ACTIVATED CARBONS [J].
RODRIGUEZREINOSO, F ;
MOLINASABIO, M ;
GONZALEZ, MT .
CARBON, 1995, 33 (01) :15-23
[40]   Control of pore development during CO2 and steam activation of olive stones [J].
Roman, S. ;
Gonzalez, J. F. ;
Gonzalez-Garcia, C. M. ;
Zamora, F. .
FUEL PROCESSING TECHNOLOGY, 2008, 89 (08) :715-720