Synthesis and assembly of Au-Pt bimetallic nanoparticles

被引:14
作者
Wang, Li [1 ]
Qi, Bin [1 ]
Sun, Lanlan [1 ]
Sun, Yujing [1 ]
Guo, Cunlan [1 ]
Li, Zhuang [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
metals and alloys; self-assembly; nanomaterials; networks; CV;
D O I
10.1016/j.matlet.2007.08.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Au-Pt bimetallic nanoparticles (NPs) were synthesized by reducing the mixture of HAuCl4 and K2PtCl6 with ethanol in the presence of cinnamic acid (C6H5CHCHCO2H, CA) through a thermal process. It was found that the isolated NPs could gradually self-assemble into chain-like structures, ultimately to 3-dimensional network nanostructures by adjusting the molar ratio of CA to K2PtCl6. Energy-dispersive Spectroscopy, X-ray photoelectron spectroscopy and X-ray diffraction was used to confirm the formation of Au-Pt bimetallic nanostructures. It was worthwhile noting that the bimetallic NPs with the novel structures prepared by our method exhibited an attractive catalytic activity for the hydrogen evolution reaction in an acidic solution. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1279 / 1282
页数:4
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