Efficient photocatalytic CO2 reduction using [Re(bpy)(CO)(3){P(OEt)(3)}](+)

被引：179

作者：

Hori, H ^{[1
]}

Johnson, FPA ^{[1
]}

Koike, K ^{[1
]}

Ishitani, O ^{[1
]}

Ibusuki, T ^{[1
]}

机构：

[1] NATL INST RESOURCES & ENVIRONM, TSUKUBA, IBARAKI 305, JAPAN

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1996年 / 96卷 / 1-3期

关键词：

rhenium bipyridine complex; triethylphosphite; CO2; reduction; photocatalyst;

D O I：

10.1016/1010-6030(95)04298-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

[Re(bpy)(CO)(3){P(OEt)(3)}](+) (1(+)) (bpy, 2,2'-bipyridine) is the most efficient homogeneous photocatalyst for the selective reduction of CO2 to CO reported to date. Both the quantum yield and turnover number of the photocatalytic reaction are strongly dependent on the irradiation light intensity and wavelength because of the unusual stability of the one-electron-reduced species [Re(bpy(.-))(CO)(3){P(OEt)(3)}] (1).

引用

页码：171 / 174

页数：4

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