Green synthesis of highly recyclable CuO/eggshell nanocomposite to efficient removal of aromatic containing compounds and reduction of 4-nitrophenol at room temperature

被引：30

作者：

Sajadi, S. Mohammad ^{[1
,2
]}

Kolo, Kamal ^{[1
]}

Abdullah, Shorish M. ^{[1
,3
]}

Hamad, Samir M. ^{[1
]}

Khalid, Hana. S. ^{[1
]}

Yassein, Ali. T. ^{[1
]}

机构：

[1] Soran Univ, Sci Res Ctr, POB 624, Soran, Kurdistan Regio, Iraq

[2] Soran Univ, Dept Petr Geosci, Fac Sci, POB 624, Soran, Kurdistan Regio, Iraq

[3] Soran Univ, Fac Sci, Dept Biol, POB 624, Soran, Kurdistan Regio, Iraq

来源：

SURFACES AND INTERFACES | 2018年 / 13卷

关键词：

Light crude oil; Green synthesis; CuO/ eggshell NCs; Catalytic activity; Recyclability; ONE-POT SYNTHESIS; CATALYTIC-ACTIVITY; HETEROGENEOUS CATALYST; COPPER NANOPARTICLES; REUSABLE CATALYST; HYDROGENATION; SILVER; PD; BIOSYNTHESIS; ENHANCEMENT;

D O I：

10.1016/j.surfin.2018.08.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The CuO/ eggshell nanocomposite (NCs) was green synthesized using the extract of the pomegranate dried peel in a green root as a novel adsorbent nanocatalyst to efficient removal of aromatic compounds of crude oil sample from Shiwashok oil field in Iraqi Kurdistan as a model. Also, it was employed to reduction of 4-nitrophenole (4NP) to 4-aminophenol (4-AP) at room temperature. The characterization of nanocomposite was using FE-SEM, EDS, elemental mapping and XRD analytical techniques. The spectrophotometrically results strongly demonstrated the excellent ability of nanocomposite on removing the aromatic containing compounds from the light crude oil sample and also reduction of 4-NP. Furthermore, the biosynthesized nano-adsorbent is quite active and stable for many cycles in both reactions. Facile and clean synthesis, simple preparation procedure, alterable supports, low cost and highly efficiency are the best features of this method.

引用

页码：205 / 215

页数：11

共 43 条

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