Ligand-Free, Palladium-Catalyzed Dihydrogen Generation from TMDS: Dehalogenation of Aryl Halides on Water

被引：57

作者：

Bhattacharjya, Anish ^{[1
]}

Klumphu, Piyatida ^{[1
]}

Lipshutz, Bruce H. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 05期

关键词：

ROOM-TEMPERATURE HYDRODEHALOGENATION; REDUCTIVE DEHALOGENATION; ELECTRON-TRANSFER; AMPHIPHILE; COUPLINGS;

D O I：

10.1021/ol5037369

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild and environmentally attractive dehalogenation of functionalized aryl halides has been developed using nanoparticles formed from PdCl2 in the presence of tetramethyldisiloxane (TMDS) on water. The active catalyst and reaction medium can be recycled. This method can also be applied to cascade reactions in a one-pot sequence.

引用

页码：1122 / 1125

页数：4

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