Microbial catalyzed esterification of primary and secondary alcohols in organic solvent

被引:25
作者
Molinari, F
Gandolfi, R
Aragozzini, F
机构
[1] Dipartimento di Scienze e Tecnologie Alimentari e Microbiologiche, Sezione Microbiologia Industriale, Università degli Studi di Milano, 20133 Milano
关键词
D O I
10.1007/BF00765191
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Microbial esterification of primary and secondary short chain alcohols with butyric acid in organic solvent has been studied. A screening for 2-octylbutyrate hydrolysis between microorganisms belonging to different genera allowed the selection of 12, microbial strains able to hydrolyze this substrate. The potential of these microorganisms in catalyzing ester formation nas checked for various 1- and 2-alkylbutyrate derivatives: Rhizopus delemar, Rhizopus oryzae and Sarcina lutea promoted both 1- and 2-alkylbutyrate synthesis with almost complete molar conversion of the primary alcohols, while Aspergillus niger and Yarrowia lipolytica only catalyzed I-alkanol esterification.
引用
收藏
页码:103 / 108
页数:6
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