Evaluation of hydrotropic pretreatment on lignocellulosic biomass

被引:42
作者
Devendra, Leena P. [1 ]
Kumar, Kiran M. [1 ]
Pandey, Ashok [1 ]
机构
[1] Natl Inst Interdisciplinary Sci & Technol CSIR, Ctr Biofuels, Trivandrum 695019, Kerala, India
关键词
Hydrotrope; Delignification; Pretreatment; Enzymatic hydrolysis; Lignin; ENHANCE ENZYMATIC-HYDROLYSIS; SUGARCANE BAGASSE; CORN STOVER; ETHANOL-PRODUCTION; ALKALINE-PEROXIDE; LIGNIN CONTENT; BIRCH WOOD; WATER; FRACTIONATION; TOPOCHEMISTRY;
D O I
10.1016/j.biortech.2016.03.059
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The production of cellulosic ethanol from biomass is considered as a promising alternative to fossil fuels, providing a sustainable option for fuels production in an environmentally compatible manner. The presence of lignin poses a significant challenge for obtaining biofuels and bioproducts from biomass. Part of that problem involves understanding fundamental aspects of lignin structure which can provide a pathway for the development of improved technologies for biomass conversion. Hydrotropic pretreatment has several attractive features that make it an attractive alternative for biofuel production. This review highlights the recent developments on hydrotropic pretreatment processes for lignocellulosic biomass on a molecular structure basis for recalcitrance, with emphasis on lignin concerning chemical structure, transformation and recalcitrance. The review also evaluates the hydrotropic delignification in comparison to alkaline delignification on lignin reduction and surface coverage by lignin. The effect of hydrotrope pretreatment on enzymatic saccharification has also been discussed. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:350 / 358
页数:9
相关论文
共 61 条
[1]  
Andelin J., 1989, Background Paper (OTA-BP-O-54), US Congress, Office of technology assessment, P74
[2]   Green hydrotropic extraction technology for delignification of sugarcane bagasse by using alkybenzene sulfonates as hydrotropes [J].
Ansari, Heed B. ;
Gaikar, Vilas G. .
CHEMICAL ENGINEERING SCIENCE, 2014, 115 :157-166
[3]   SPECTROGRAPHIC CONTRIBUTIONS TO LIGNIN CHEMISTRY .9. ABSORPTION PROPERTIES OF SOME 4-HYDROXYPHENYL GUAIACYL AND 4-HYDROXY-3,5-DIMETHOXYPHENYL TYPE MODEL COMPOUNDS FOR HARDWOOD LIGNINS [J].
AULINERDTMAN, G ;
SANDEN, R .
ACTA CHEMICA SCANDINAVICA, 1968, 22 (04) :1187-+
[4]   Alkaline peroxide pretreatment of corn stover: effects of biomass, peroxide, and enzyme loading and composition on yields of glucose and xylose [J].
Banerjee, Goutami ;
Car, Suzana ;
Scott-Craig, John S. ;
Hodge, David B. ;
Walton, Jonathan D. .
BIOTECHNOLOGY FOR BIOFUELS, 2011, 4
[5]   THE BIOLOGICAL DEGRADATION OF CELLULOSE [J].
BEGUIN, P ;
AUBERT, JP .
FEMS MICROBIOLOGY REVIEWS, 1994, 13 (01) :25-58
[6]   Characterisation of structure-dependent functional properties of lignin with infrared spectroscopy [J].
Boeriu, CG ;
Bravo, D ;
Gosselink, RJA ;
van Dam, JEG .
INDUSTRIAL CROPS AND PRODUCTS, 2004, 20 (02) :205-218
[7]   Comparison of the effects of five pretreatment methods on enhancing the enzymatic digestibility and ethanol production from sweet sorghum bagasse [J].
Cao, Weixing ;
Sun, Chen ;
Liu, Ronghou ;
Yin, Renzhan ;
Wu, Xiaowu .
BIORESOURCE TECHNOLOGY, 2012, 111 :215-221
[8]   Is sodium cinnamate a photoswitchable hydrotrope? [J].
Devendra, Leena P. ;
Gaikar, Vilas G. .
JOURNAL OF MOLECULAR LIQUIDS, 2012, 165 :71-77
[9]   Lignification and lignin topochemistry - an ultrastructural view [J].
Donaldson, LA .
PHYTOCHEMISTRY, 2001, 57 (06) :859-873
[10]  
Dutta A., 2017, Spectroscopic Methods for Nanomaterials Characterization, P73, DOI [DOI 10.1016/B978-0-323-46140-5.00004-2, DOI 10.1007/978-3-642-74065-7_16]