Application of Electrospray ionization mass spectrometry to the elucidation of the primary structure of lignin

被引：62
|
作者：
Evtuguin, DV [1 ]
Amado, FML [1 ]
机构：
[1] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal
来源：
MACROMOLECULAR BIOSCIENCE | 2003年 / 3卷 / 07期
关键词：
biopolymers; electrospray ionization; lignin; mass spectrometry; structure;
D O I：
10.1002/mabi.200350006
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Electrospray ionization mass spectrometry (ESI-MS) was successfully applied to the structural analysis of lignin. The structure of oligomers fractionated from Eucalyptus globulus dioxane lignin was elucidated using tandem mass spectrometry, and the information on fragmentation patterns was provided by experiments on dimeric model compounds. Data obtained revealed a significant abundance in the lignin macromolecules of linear fragments that were composed of 8-O-4' linked syringyl/guaiacyl units and syringaresinol.
引用
收藏
页码：339 / 343
页数：5
相关论文
共 50 条
  • [41] Radical ion generation processes of organic compounds in electrospray ionization mass spectrometry
    Vessecchi, R.
    Crotti, A. E. M.
    Guaratini, T.
    Colepicolo, P.
    Galembeck, S. E.
    Lopes, N. P.
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2007, 4 (01) : 75 - 87
  • [42] Complexation of malic acid with cadmium(II) probed by electrospray ionization mass spectrometry
    Dytrtova, Jana Jaklova
    Jakl, Michal
    Schroeder, Detlef
    TALANTA, 2012, 90 : 63 - 68
  • [43] Analysis of microcystins by capillary zone electrophoresis coupling with electrospray ionization mass spectrometry
    Tong, Ping
    Zhang, Lan
    He, Yu
    Tang, Shurong
    Cheng, Jintian
    Chen, Guonan
    TALANTA, 2010, 82 (04) : 1101 - 1106
  • [44] Electrospray Ionization-Mass Spectrometry for Molecular Level Understanding of Polymer Degradation
    Hakkarainen, Minna
    MASS SPECTROMETRY OF POLYMERS - NEW TECHNIQUES, 2012, 248 : 175 - 204
  • [45] Studies on anhydroicaritin by electrospray ionization multi-stage tandem mass spectrometry
    Dou, JP
    Liu, ZQ
    Liu, SY
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2003, 31 (12) : 1433 - 1436
  • [46] Microfabricated isoelectric focusing device for direct electrospray ionization-mass spectrometry
    Wen, J
    Lin, YH
    Xiang, F
    Matson, DW
    Udseth, HR
    Smith, RD
    ELECTROPHORESIS, 2000, 21 (01) : 191 - 197
  • [47] Real-time analysis of living animals by electrospray ionization mass spectrometry
    Yoshimura, Kentaro
    Chen, Lee Chuin
    Yu, Zhan
    Hiraoka, Kenzo
    Takeda, Sen
    ANALYTICAL BIOCHEMISTRY, 2011, 417 (02) : 195 - 201
  • [48] Unravelling seemingly complex chemistry of reactions using electrospray ionization mass spectrometry
    Bakhtiar, R
    Hop, CECA
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1999, 12 (07) : 511 - 527
  • [49] Recent Approaches for Chemical Speciation and Analysis by Electrospray Ionization (ESI) Mass Spectrometry
    Indelicato, Serena
    Bongiorno, David
    Ceraulo, Leopoldo
    FRONTIERS IN CHEMISTRY, 2021, 8
  • [50] An electrospray-ionization mass spectrometry analysis of triacylglycerols in developing corn kernels
    Harrabi, Saoussem
    Boukhchina, Sadok
    Kallel, Habib
    Mayer, Paul M.
    CANADIAN JOURNAL OF ANALYTICAL SCIENCES AND SPECTROSCOPY, 2008, 53 (01): : 22 - 27
12345