The effect of water on the yield and structure of the products of brown coal pyrolysis and hydrogenation

被引：13

作者：

Butuzova, L

Razvigorova, M

Krzton, A

Minkova, V

机构：

[1] Natl Acad Sci Ukraine, LM Litvinenko Inst Phys Organ & Coal Chem, UA-340114 Donetsk, Ukraine

[2] Bulgarian Acad Sci, Inst Organ Chem, BU-1113 Sofia, Bulgaria

[3] Polish Acad Sci, Inst Coal Chem, PL-44102 Gliwice, Poland

来源：

FUEL | 1998年 / 77卷 / 06期

关键词：

brown coal; water; pyrolysis; hydrogenation;

D O I：

10.1016/S0016-2361(97)00212-3

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The influence of various methods of Kansko-Achinsk brown coals humidification on their behaviour during pyrolysis and hydrogenation is investigated. Variations of derivatographic data, X-ray and DRIFT features of solid pyrolysis residues are presented. The hydrogenation liquid and gas products are studied by gas chromatography, gas chromatography-mass spectrometry and (NMR)-N-1 spectroscopy. It was shown that part of the moisture is irreversibly bound with coal, which participates in thermal hydrolysis reactions and produces the change in the polycyclic aromatic skeleton which is accompanied by a greater change in the yield of pyrolysis and hydrogenation products. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：639 / 643

页数：5

共 6 条

[1]

GERGOVA K, 1993, J CHEM TECH BIOTECHN, V53, P301

[2]

KRICHKO AA, 1980, KHIMIYA TVORDOGO TOP, V6, P3

[3] EFFECT OF WATER-VAPOR ON THE PYROLYSIS OF SOLID FUELS .1. EFFECT OF WATER-VAPOR DURING THE PYROLYSIS OF SOLID FUELS ON THE YIELD AND COMPOSITION OF THE LIQUID PRODUCTS [J].