Resorcinol formaldehyde hydrogel: Synthesis, polymerization, and application in ceramic gel-casting

被引：4

作者：

Ren, Quanxing ^{[1
,2
]}

Sun, Rui ^{[1
,2
]}

Feng, Dong ^{[1
,2
]}

Ru, Hongqiang ^{[1
,2
]}

Wang, Wei ^{[1
,2
]}

Zhang, Cuiping ^{[1
,2
]}

机构：

[1] Northeastern Univ, Key Lab Anisotropy & Texture Mat, Minist Educ, Shenyang 110819, Liaoning, Peoples R China

[2] Northeastern Univ, Inst Adv Ceram, Sch Mat Sci & Engn, Shenyang 110819, Peoples R China

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2022年 / 647卷

基金：

中国国家自然科学基金;

关键词：

Ceramics; Gel-casting; Catalyst; Mechanical properties; MECHANICAL-PROPERTIES; BORON-CARBIDE; CARBON AEROGELS; FABRICATION; POROSITY; PARTICLE; PREFORM; RESINS;

D O I：

10.1016/j.colsurfa.2022.129192

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present study, resorcinol formaldehyde (RF) hydrogel was successfully synthesized and applied in the gel-casting process. The polymerization of the gel system and the effects of catalysts on the mechanical properties of the ceramic preform were investigated. Changing the type of catalyst to control the gel reaction rate enabled the in situ "immobilization " of the B4C particles, thereby enabling the preparation of B4C/C porous preforms with a uniform structure and controllable pore size. The results revealed that using Na2CO3, having a high polarizing power Na+ and a high degree of hydrolysis CO32-, as a catalyst, the B4C/C porous preforms with low porosity and best mechanical properties can be obtained. Further, the flexural strength and compressive strength could reach 21.2 MPa and 52.2 MPa, respectively.

引用

页数：8

共 35 条

[1] Alumina gelcasting with a new low-toxicity system [J].

Cai, K ;

Huang, Y ;

Yang, JL .

HIGH-PERFORMANCE CERAMICS 2001, PROCEEDINGS, 2002, 224-2 :643-646

[2] Boron Carbide: Structure, Properties, and Stability under Stress [J].

Domnich, Vladislav ;

Reynaud, Sara ;

Haber, Richard A. ;

Chhowalla, Manish .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (11) :3605-3628

[3] Advances in Tailoring Resorcinol-Formaldehyde Organic and Carbon Gels [J].

ElKhatat, Ahmed M. ;

Al-Muhtaseb, Shaheen A. .

ADVANCED MATERIALS, 2011, 23 (26) :2887-2903

[4] Porosity and surface area of monolithic carbon aerogels prepared using alkaline carbonates and organic acids as polymerization catalysts [J].

Fairen-Jimenez, D. ;

Carrasco-Marin, F. ;

Moreno-Castilla, C. .

CARBON, 2006, 44 (11) :2301-2307

[5] A novel gel-cast SiC with potential application in turbine hot section: Investigation of the rheological behavior and mechanical properties [J].

Fallah-Arani, Hesam ;

Isafi, Salah ;

Tabrizian, Parinaz ;

Moakhar, Roozbeh Siavash ;

Baghshahi, Saeid .

CERAMICS INTERNATIONAL, 2019, 45 (13) :15996-16001

[6] Phenolic resins .2. Influence of catalyst type on reaction mechanisms and kinetics [J].

GrenierLoustalot, MF ;

Larroque, S ;

Grande, D ;

Grenier, P ;

Bedel, D .

POLYMER, 1996, 37 (08) :1363-1369

[7] Effect of Monomers Content and their Ratio on Gelcasting of Fused Silica Ceramics [J].

Kandi, Kishore Kumar ;

Punugupati, Gurabvaiah ;

Pal, Sumit Kumar ;

Chilakalapalli, Surya Prakash Rao .

TRANSACTIONS OF THE INDIAN CERAMIC SOCIETY, 2016, 75 (03) :185-188

[8] Recent advances in preparations and applications of carbon aerogels: A review [J].

Lee, Jong-Hoon ;

Park, Soo-Jin .

CARBON, 2020, 163 :1-18

[9] Preparation of dense B4C ceramics by spark plasma sintering of high-purity nanoparticles [J].

Li, Penghui ;

Ma, Mengdong ;

Wu, Yingju ;

Zhang, Xiang ;

Chang, Yukai ;

Zhuge, Zewen ;

Sun, Lei ;

Hu, Wentao ;

Yu, Dongli ;

Xu, Bo ;

Zhao, Zhisheng ;

Chen, Junyun ;

He, Julong ;

Tian, Yongjun .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2021, 41 (07) :3929-3936

[10] Mechanism of Base-Catalyzed Resorcinol-Formaldehyde and Phenol-Resorcinol-Formaldehyde Condensation Reactions: A Theoretical Study [J].

Li, Taohong ;

Cao, Ming ;

Liang, Jiankun ;

Xie, Xiaoguang ;

Du, Guanben .

POLYMERS, 2017, 9 (09)

← 1 2 3 4 →