Uptake of copper(II) by wool

被引:18
作者
Sheffield, A [1 ]
Doyle, MJ [1 ]
机构
[1] Allegheny Coll, Dept Chem, Meadville, PA 16335 USA
关键词
D O I
10.1177/004051750507500303
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
The uptake of copper(II) onto wool from aqueous solutions of copper(II) sulfate is investigated as a function of treatment time and temperature, amount of copper applied, and pH. Longer heating times and. higher temperatures lead to increased uptake: I hour near the boil gives optimal results. Increasing the amount of applied copper increases the total uptake, but the fraction of applied copper taken up decreases with the amount applied. As pH is increased, copper uptake increases linearly with pH up to a pH of approximately 6; above pH 6, solid copper salts are precipitated. The possibility of specific buffer interference with copper uptake is discussed.
引用
收藏
页码:203 / 207
页数:5
相关论文
共 15 条
[1]  
ASPLAND JR, 1997, TEXTILE DYEING COLOR, P40
[2]  
Baughman GL, 2001, AATCC REV, V1, P32
[3]  
BUCHANAN R, 1995, DYERS GARDEN, P37
[4]  
Carrin G, 1987, Int J Health Plann Manage, V2, P125
[5]  
Dedhia EM., 1998, COLOURAGE, V45, P45
[6]   BINDING OF COPPER(2) TO MOHAIR KERATIN [J].
GUTHRIE, RE ;
LAURIE, SH .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1968, 21 (10) :2437-&
[7]  
HARRIS DC, 2003, QUANTITATIVE CHEM AN, pAP11
[8]   Noncomplexing tertiary amines as "better" buffers covering the range of pH 3-11. Temperature dependence of their acid dissociation constants [J].
Kandegedara, A ;
Rorabacher, DB .
ANALYTICAL CHEMISTRY, 1999, 71 (15) :3140-3144
[9]   Deodorant properties of wool fabrics dyed with acid mordant dyes and a copper salt [J].
Kobayashi, Y ;
Nakanishi, T ;
Komiyama, J .
TEXTILE RESEARCH JOURNAL, 2002, 72 (02) :125-131
[10]   ELECTRON-SPIN RESONANCE STUDY OF COPPER (II) INTERACTION WITH WOOL-KERATIN .2. INTERPRETATION AND PROPERTIES OF A COPPER (II)/WOOL ESR-SPECTRUM [J].
KOKOT, S ;
GOLDING, RM ;
FEUGHELM.M .
TEXTILE RESEARCH JOURNAL, 1972, 42 (12) :704-&