Triaqua(2,2′-bipyridine-κ2N,N′)(3-carboxyphenoxyacetato-κO)manganese(II) 3-carboxyphenoxyacetate monohydrate

被引:4
作者
Zhang, XF [1 ]
Gao, S [1 ]
Huo, LH [1 ]
Zhao, JG [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Lab Funct Mat, Harbin 150080, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词
D O I
10.1107/S1600536805035336
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Mn(C9H7O5)(C10H8N2)(H2O)(3)]-( C9H7O5)(H2O)-H-. or [Mn(3-CPOAH(-))(2,2'-bipy)(H2O)(3)]-( 3-CPOAH(-))(H2O)-H-. (where 3-CPOAH(-) is the 3-carboxy-phenoxyacetate monoanion and 2,2'-bipy is 2,2'-bipyridine), the Mn-II ion has a distorted octahedral geometry involving one O atom of the 3-CPOAH(-) group, two N atoms of the 2,2'-bipy ligand and three water molecules. A three-dimensional supramolecular network is constructed via O - H (...) O hydrogen-bonding and pi - pi stacking interactions.
引用
收藏
页码:M2471 / M2473
页数:3
相关论文
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ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M33-M35