Texture Regulation of Metal-Organic Frameworks, Microwave Absorption Mechanism-Oriented Structural Optimization and Design Perspectives

被引：120

作者：

Gao, Zhenguo ^{[1
,2
,3
]}

Iqbal, Aamir ^{[2
]}

Hassan, Tufail ^{[2
]}

Zhang, Limin ^{[1
]}

Wu, Hongjing ^{[1
]}

Koo, Chong Min ^{[2
,3
,4
]}

机构：

[1] Northwestern Polytech Univ, MOE Key Lab Mat Phys & Chem Extraordinary, Xian 710072, Peoples R China

[2] SungKyunKwan Univ, Sch Adv Mat Sci & Engn, Seobu Ro 2066, Suwon 16419, Gyeonggi Do, South Korea

[3] Korea Inst Sci & Technol KIST, Mat Architecturing Res Ctr, Seoul 02792, South Korea

[4] SungKyunKwan Univ, Sch Chem Engn, Seobu Ro 2066, Suwon 16419, Gyeonggi Do, South Korea

来源：

ADVANCED SCIENCE | 2022年 / 9卷 / 35期

基金：

美国国家科学基金会; 新加坡国家研究基金会;

关键词：

electromagnetic wave absorption; metal-organic frameworks (MOFs); optimization engineering; texture regulation; ELECTROMAGNETIC-WAVE ABSORPTION; TUNABLE CHEMICAL-COMPOSITION; HETEROGENEOUS INTERFACES; FACILE SYNTHESIS; MOF; COMPOSITES; EFFICIENT; CO; LIGHTWEIGHT; NANOCOMPOSITES;

D O I：

10.1002/advs.202204151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Texture regulation of metal-organic frameworks (MOFs) is essential for controlling their electromagnetic wave (EMW) absorption properties. This review systematically summarizes the recent advancements in texture regulation strategies for MOFs, including etching and exchange of central ions, etching and exchange of ligands, chemically induced self-assembly, and MOF-on-MOF heterostructure design. Additionally, the EMW absorption mechanisms in approaches based on structure-function dependencies, including nano-micro topological engineering, defect engineering, interface engineering, and hybrid engineering, are comprehensively explored. Finally, current challenges and future research orientation are proposed. This review aims to provide new perspectives for designing MOF-derived EMW-absorption materials to achieve essential breakthroughs in mechanistic investigations in this promising field.

引用

页数：27

共 158 条

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