Effect of aluminum addition on the optical, morphology and electrical behavior of spin coated zinc oxide thin films

被引:18
作者
Srivastava, Amit Kumar [1 ]
Kumar, Jitendra [1 ]
机构
[1] Indian Inst Technol Kanpur, Mat Sci Programme, Kanpur 208016, Uttar Pradesh, India
关键词
TRANSPARENT; ZNO;
D O I
10.1063/1.3640406
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Aluminum-doped ZnO thin films of high optical transmittance (similar to 84-100%) and low resistivity (similar to 2.3x10(-2) Omega cm) have been prepared on glass substrate by the spin coating and subsequent annealing at 500 degrees C for 1h in air or vacuum. Effect of aluminum doping and annealing environment on morphology, optical transmittance and electrical resistivity of ZnO thin films has been studied with possible application as a transparent electrode in photovoltaic. The changes occurring due to aluminum addition include reduction in grain size, root mean square roughness, peak-valley separation, and sheet resistance with improvement in the optical transmittance to 84-100% in the visible range. The origin of low electrical resistivity lies in increase in i) electron concentration following aluminum doping (being trivalent), formation of oxygen vacancies due to vacuum annealing, filling of cation site with additional zinc at solution stage itself and ii) carrier mobility. Copyright 2011 Author(s). This article is distributed under a Creative Commons Attribution 3.0 Unported License. [doi: 10.1063/1.3640406]
引用
收藏
页数:10
相关论文
共 38 条
[1]   Low-cost embedded capacitor technology with hydrothermal and sol-gel processes [J].
Abothu, IR ;
Raj, PM ;
Balaraman, D ;
Sacks, MD ;
Bhattacharya, S ;
Tummala, RR .
9TH INTERNATIONAL SYMPOSIUM ON ADVANCED PACKAGING MATERIALS: PROCESSES, PROPERTIES AND INTERFACES, 2004 PROCEEDINGS, 2004, :78-83
[2]   Preparation and properties of transparent conductive aluminum-doped zinc oxide thin films by sol-gel process [J].
Alam, MJ ;
Cameron, DC .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 2001, 19 (04) :1642-1646
[3]   Electrical and optical properties of ultrasonically sprayed Al-doped zinc oxide thin films [J].
Babu, B. J. ;
Maldonado, A. ;
Velumani, S. ;
Asomoza, R. .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2010, 174 (1-3) :31-37
[4]   The properties of aluminum-doped zinc oxide thin films prepared by rf-magnetron sputtering from nanopowder targets [J].
Ben Ayadi, Z. ;
El Mir, L. ;
Djessas, K. ;
Alaya, S. .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2008, 28 (5-6) :613-617
[5]  
Coleman VA, 2006, ZINC OXIDE BULK, THIN FILMS AND NANOSTRUCTURES: PROCESSING, PROPERTIES AND APPLICATIONS, P1, DOI 10.1016/B978-008044722-3/50001-4
[6]  
Cullity B.D., 1956, Elements of X- ray Diffraction, P99
[7]   Electronic oxide polarizability and optical basicity of simple oxides .1. [J].
Dimitrov, V ;
Sakka, S .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (03) :1736-1740
[8]   Role of defects in tailoring structural, electrical and optical properties of ZnO [J].
Dutta, Sreetama ;
Chattopadhyay, S. ;
Sarkar, A. ;
Chakrabarti, Mahuya ;
Sanyal, D. ;
Jana, D. .
PROGRESS IN MATERIALS SCIENCE, 2009, 54 (01) :89-136
[9]   Transparent conducting oxides for photovoltaics [J].
Fortunato, Elvira ;
Ginley, David ;
Hosono, Hideo ;
Paine, David C. .
MRS BULLETIN, 2007, 32 (03) :242-247
[10]   Effects of substrate temperature on the optical and electrical properties of Al:ZnO films [J].
Fournier, Carrie ;
Bamiduro, O. ;
Mustafa, H. ;
Mundle, R. ;
Konda, R. B. ;
Williams, F. ;
Pradhan, A. K. .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2008, 23 (08) :085019