Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

被引：96

作者：

Liu, Hongli ^{[1
]}

Yin, Biaolin ^{[1
]}

Gao, Zhiqiang ^{[1
]}

Li, Yingwei ^{[1
]}

Jiang, Huanfeng ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 14期

关键词：

ORGANIC FRAMEWORK; COUPLING REACTIONS; NANOPARTICLES; HETEROCYCLES; ACTIVATION; CHLORIDES; BUTOXIDE; BENZENE; PROMOTE;

D O I：

10.1039/c2cc16790e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel heterogeneous catalysis system using metal-organic frameworks as catalyst demonstrated excellent chemo- and regioselectivity for the direct arylation of unactivated arenes with aryl iodides/bromides without the assistance of any transition metals.

引用

页码：2033 / 2035

页数：3

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