Synthesis, structure and luminescent properties of Cd(II) and Zn(II) complexes constructed from 3,5-dimethyl-2, 6-pyrazinedicarboxylic acid

被引：1
|
作者：
Sun, Ya-Guang [1 ]
Gu, Xiao-Fu [1 ]
Drozdzak, Renata [2 ]
Ding, Fu [2 ]
Gao, En-Jun [1 ]
Yan, Xiao-Mei [1 ]
Verpoort, Francis [2 ]
机构：
[1] Shenyang Inst Chem Technol, Lab Coordinat Chem, Shenyang, Peoples R China
[2] Univ Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 12期
基金：
中国国家自然科学基金;
关键词：
water cluster; supramolecular; self-assembly; hydrogen bond;
D O I：
10.1080/00958970701793610
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Cd-2(phen)(2)(DPZDA)(2)(H2O)(2)] center dot 8H(2)O (1) and [Zn(phen)(DPZDA)(H2O)] center dot 2H(2)O (2) have been synthesized by reaction of Cd(NO3)(2)/Zn(NO3)(2) with phen and DPZDA (where phen = 1,10-phenanthroline, H(2)DPZDA = 3,5-dimethyl-2,6-pyrazinedicarboxylic acid) in aqueous ethanol solution. Elemental analysis, IR spectra, thermal analyses and X-ray single crystal diffraction were carried out to determine the composition and crystal structure of 1 and 2. In 1, a 2D supramolecular network containing a novel metal-water decamer were formed by hydrogen bonds. In 2, a 2D supramolecular structure was constructed from hydrogen bonds and pi...pi interactions. Moreover, 1 and 2 displayed photoluminescent properties in the blue range at room temperature.
引用
收藏
页码：1839 / 1848
页数：10
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