Novel Zn(II) coordination polymer based on 1,2-bis (4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

被引：1
作者：
Wang, Huaishan [1 ]
Szeto, Lap [2 ]
Chan, Wesley Ting Kwok [1 ]
Yeung, Ho-Lun [1 ]
Wong, Ka-Leung [3 ]
Wong, Wing-Tak [1 ]
机构：
[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, Dept Chem, Pokfulam, Hong Kong, Peoples R China
[3] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2012年 / 90卷 / 01期
关键词：
metal organic framework; coordination polymer; 1,2-bis(4-pyridyl)hydrazine; interpenetrating polymer; microporous; hydrogen bond; CRYSTAL-STRUCTURES; HYDRAZO COMPOUNDS; TRANSFER HYDROGENATION; AZO-COMPOUNDS; RANEY-NICKEL; COMPLEXES; AZOBENZENE; EXCHANGE;
D O I：
10.1139/V11-132
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two MOFs were reported based on Zn(H) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn-2(L1)(2)(L2)(2)](infinity) was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn-2(L1)(2)(L3)(2)](infinity), was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF H consists of large porosity with a total volume of 3746 angstrom(3) that occupies 34.1% of the unit cell.
引用
收藏
页码：100 / 107
页数：8
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