Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

被引：155

作者：

Ackermann, Lutz ^{[1
]}

Diers, Emelyne ^{[1
]}

Manvar, Atul ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 04期

关键词：

PHOSPHINE OXIDES; ARYL; FUNCTIONALIZATION; ACTIVATION; PRELIGANDS; PALLADIUM; PHENOLS; BROMIDES; SYSTEM;

D O I：

10.1021/ol3000876

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium-catalyzed direct arylations of phenols bearing removable directing groups were accomplished through carboxylate assistance via six-membered ruthenacycles as key intermediates.

引用

页码：1154 / 1157

页数：4

共 60 条

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