Physico-Mechanical Properties of Biodegradable Rubber Toughened Polymers

被引:40
作者
Farsetti, S. [1 ]
Cioni, B. [1 ]
Lazzeri, A. [1 ]
机构
[1] Univ Pisa, Dept Chem Engn Ind Chem & Mat Sci, I-56126 Pisa, Italy
来源
EUROFILLERS | 2011年 / 301卷
关键词
biodegradable; biopolymers; blends; mechanical properties; POLY(LACTIC ACID); POLY(BUTYLENE ADIPATE-CO-TEREPHTHALATE); MECHANICAL-PROPERTIES; BLENDS; PLA; MISCIBILITY; POLY(L-LACTIDE); PLASTICIZERS; COPOLYMER; GLYCOL);
D O I
10.1002/masy.201150311
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, blends of poly(lactic acid) (PLA) with poly(butylene adipate-co-terephthalate) (PBAT) were studied for their mechanical and thermal properties as a function of the PBAT content. Tensile testing, impact testing, differential scanning calorimetry (DSC), dynamic mechanical analysis (DMTA) and scanning electron microscopy (SEM) were used to characterize the blends. It was observed that PLA/PBAT blends maintained quite high modulus and tensile strength compared to pure PLA. Small amounts of PBAT improved the elongation at break and the impact resistance showing a debonding effect typical of rubber toughened systems.
引用
收藏
页码:82 / 89
页数:8
相关论文
共 27 条
[1]   Structure and mechanical properties of poly(D,L-lactic acid)/poly(ε-caprolactone) blends [J].
Broz, ME ;
VanderHart, DL ;
Washburn, NR .
BIOMATERIALS, 2003, 24 (23) :4181-4190
[2]  
Bucknall C.B., 1977, TOUGHENED POLYM
[3]   Miscibility and mechanical properties of blends of (L)-lactide copolymers with atactic poly(3-hydroxybutyrate) [J].
Focarete, ML ;
Scandola, M ;
Dobrzynski, P ;
Kowalczuk, M .
MACROMOLECULES, 2002, 35 (22) :8472-8477
[4]   Miscibility and biodegradability of blends of poly(lactic acid) and poly(vinyl acetate) [J].
Gajria, AM ;
Dave, V ;
Gross, RA ;
McCarthy, SP .
POLYMER, 1996, 37 (03) :437-444
[5]  
Hatakeyama T., 1994, THERMAL ANAL FUNDAME
[6]   Synthesis and characterization of TPO-PLA copolymer and its behavior as compatibilizer for PLA/TPO blends [J].
Ho, Chang-Hong ;
Wang, Chau-Hui ;
Lin, Chin-I ;
Lee, Yu-Der .
POLYMER, 2008, 49 (18) :3902-3910
[7]   Study of biodegradable polyactide/poly(butylene adipate-co-terephthalate) blends [J].
Jiang, L ;
Wolcott, MP ;
Zhang, JW .
BIOMACROMOLECULES, 2006, 7 (01) :199-207
[8]   Reactive blending of biodegradable polymers: PLA and starch [J].
Jun, CL .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2000, 8 (01) :33-37
[9]  
Labrecque LV, 1997, J APPL POLYM SCI, V66, P1507, DOI 10.1002/(SICI)1097-4628(19971121)66:8<1507::AID-APP11>3.0.CO
[10]  
2-0